Fluctuations and asymmetry via local Lyapunov instability in the time-reversible doubly thermostated harmonic oscillator

Forward and backward trajectories from time-symmetric equations of motion can have time-asymmetric stability properties, and exhibit time-asymmetric fluctuations. Away from equilibrium this symmetry breaking is the mechanical equivalent of the second law of thermodynamics. Strange attractor states o...

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Veröffentlicht in:The Journal of chemical physics 2001-10, Vol.115 (13), p.5744-5750
Hauptverfasser: Hoover, Wm. G., Posch, H. A., Hoover, Carol G.
Format: Artikel
Sprache:eng
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Zusammenfassung:Forward and backward trajectories from time-symmetric equations of motion can have time-asymmetric stability properties, and exhibit time-asymmetric fluctuations. Away from equilibrium this symmetry breaking is the mechanical equivalent of the second law of thermodynamics. Strange attractor states obeying the second law are time-reversed versions of (unobservable) repeller states which violate that law. Here, we consider both the equilibrium and the nonequilibrium cases for a simple deterministically thermostated oscillator. At equilibrium the extended phase-space distribution is a smooth Gaussian function. Away from equilibrium the distribution is instead a fractal strange attractor. In both cases we illustrate local time-symmetry breaking. We also quantify the forward–backward fluctuation asymmetry for the thermostated oscillator.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1401158