Fluctuations and asymmetry via local Lyapunov instability in the time-reversible doubly thermostated harmonic oscillator
Forward and backward trajectories from time-symmetric equations of motion can have time-asymmetric stability properties, and exhibit time-asymmetric fluctuations. Away from equilibrium this symmetry breaking is the mechanical equivalent of the second law of thermodynamics. Strange attractor states o...
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Veröffentlicht in: | The Journal of chemical physics 2001-10, Vol.115 (13), p.5744-5750 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Forward and backward trajectories from time-symmetric equations of motion can have time-asymmetric stability properties, and exhibit time-asymmetric fluctuations. Away from equilibrium this symmetry breaking is the mechanical equivalent of the second law of thermodynamics. Strange attractor states obeying the second law are time-reversed versions of (unobservable) repeller states which violate that law. Here, we consider both the equilibrium and the nonequilibrium cases for a simple deterministically thermostated oscillator. At equilibrium the extended phase-space distribution is a smooth Gaussian function. Away from equilibrium the distribution is instead a fractal strange attractor. In both cases we illustrate local time-symmetry breaking. We also quantify the forward–backward fluctuation asymmetry for the thermostated oscillator. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.1401158 |