Spectroscopic signatures of bond-breaking internal rotation. I. Saddle point induced polyad breakdown

With the input of order 10–20 000 cm−1 of vibrational energy, the hydrogen atoms in small gas-phase molecules such as HCN, HCP, and acetylene can undergo internal rotation about the heavy-atom core (CN–CP–CC), breaking and reforming covalent bonds in the process. This article investigates the quantu...

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Veröffentlicht in:	The Journal of chemical physics 2001-01, Vol.114 (1), p.250-261
Hauptverfasser:	Jacobson, Matthew P., Child, Mark S.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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