Relationship between optical and structural properties in substituted quaterthiophene crystals

Relationship between optical and structural properties in substituted quaterthiophene crystals

The optical properties of polysubstituted α-conjugated quaterthiophene crystals display marked differences depending on substitution pattern and molecular conformation. The combination of optical spectroscopy and x-ray diffraction elucidates the correlation among molecular functionalization, crystal...

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Veröffentlicht in:Applied physics letters 1998-10, Vol.73 (17), p.2414-2416
Hauptverfasser: Gigli, G., Lomascolo, M., Cingolani, R., Barbarella, G., Zambianchi, M., Antolini, L., Della Sala, F., Di Carlo, A., Lugli, P.
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container_end_page 2416
container_issue 17
container_start_page 2414
container_title Applied physics letters
container_volume 73
creator Gigli, G.
Lomascolo, M.
Cingolani, R.
Barbarella, G.
Zambianchi, M.
Antolini, L.
Della Sala, F.
Di Carlo, A.
Lugli, P.
description The optical properties of polysubstituted α-conjugated quaterthiophene crystals display marked differences depending on substitution pattern and molecular conformation. The combination of optical spectroscopy and x-ray diffraction elucidates the correlation among molecular functionalization, crystalline structure, and electronic states. The data are quantitatively interpreted by a semiempirical technique that provides the excited state energies starting from the measured molecular geometry.
doi_str_mv 10.1063/1.122451
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title Relationship between optical and structural properties in substituted quaterthiophene crystals
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