The optical gain mechanism in solid conjugated polymers

We report on stimulated emission from a solid conjugated methyl-substituted ladder-type poly(paraphenylene). The threshold for stimulated emission as well as the spectral narrowing is measured. Upon exciting within the low energy tail of the S1-S0 (0–0) absorption band narrow emission lines offset f...

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Veröffentlicht in:Applied physics letters 1998-06, Vol.72 (23), p.2933-2935
Hauptverfasser: Schweitzer, B., Wegmann, G., Giessen, H., Hertel, D., Bässler, H., Mahrt, R. F., Scherf, U., Müllen, K.
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container_end_page 2935
container_issue 23
container_start_page 2933
container_title Applied physics letters
container_volume 72
creator Schweitzer, B.
Wegmann, G.
Giessen, H.
Hertel, D.
Bässler, H.
Mahrt, R. F.
Scherf, U.
Müllen, K.
description We report on stimulated emission from a solid conjugated methyl-substituted ladder-type poly(paraphenylene). The threshold for stimulated emission as well as the spectral narrowing is measured. Upon exciting within the low energy tail of the S1-S0 (0–0) absorption band narrow emission lines offset from the excitation by the energies of the dominant vibrational modes are observed. From these measurements we conclude that vibronic sublevels play a major role in the optical gain mechanism. Hence, the gain mechanism can be explained in terms of molecularly excited states.
doi_str_mv 10.1063/1.121498
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title The optical gain mechanism in solid conjugated polymers
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