A Convenient Procedure for Transformation of Tertiary Cyclopropanols into 5-Substituted Isoxazoles

Abstract Tertiary cyclopropanols, when treated with an excess of amyl nitrite at room temperature, are smoothly converted into dimeric β-nitrosoketones. Heating the methanolic solutions of the latter under reflux gives 5-substituted isoxazoles in good yields.

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Veröffentlicht in:	Synlett 2006-12, Vol.2006 (20), p.3427-3430
Hauptverfasser:	Churykau, Dzmitry H., Kulinkovich, Oleg G.
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Sprache:	eng
Schlagworte:	letter
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description	Abstract Tertiary cyclopropanols, when treated with an excess of amyl nitrite at room temperature, are smoothly converted into dimeric β-nitrosoketones. Heating the methanolic solutions of the latter under reflux gives 5-substituted isoxazoles in good yields.
doi_str_mv	10.1055/s-2006-956475
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title	A Convenient Procedure for Transformation of Tertiary Cyclopropanols into 5-Substituted Isoxazoles
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