Synthesis, Cross-Coupling, and Anionic Cyclization of ortho-Substituted Naphthaleneboronic Esters

Synthesis, Cross-Coupling, and Anionic Cyclization of ortho-Substituted Naphthaleneboronic Esters

Abstract 1-Fluoro-, 1-chloro- and 1-cyanonaphthalene were lithiated and then borylated at the 2-position. The 1-substituted naphthaleneboronic esters were cross-coupled with aryl halides to give 2-aryl-1-fluoro-, 2-aryl-1-chloro- and 2-aryl-1-cyanonaphthalenes. The 2-aryl-1-cyano- and 2-aryl-1-fluor...

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Veröffentlicht in:Synthesis (Stuttgart) 2006-10, Vol.2006 (20), p.3478-3484
Hauptverfasser: Lysén, Morten, Madden, Maurice, Kristensen, Jesper Langgaard, Vedsø, Per, Zøllner, Camilla, Begtrup, Mikael
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container_end_page 3484
container_issue 20
container_start_page 3478
container_title Synthesis (Stuttgart)
container_volume 2006
creator Lysén, Morten
Madden, Maurice
Kristensen, Jesper Langgaard
Vedsø, Per
Zøllner, Camilla
Begtrup, Mikael
description Abstract 1-Fluoro-, 1-chloro- and 1-cyanonaphthalene were lithiated and then borylated at the 2-position. The 1-substituted naphthaleneboronic esters were cross-coupled with aryl halides to give 2-aryl-1-fluoro-, 2-aryl-1-chloro- and 2-aryl-1-cyanonaphthalenes. The 2-aryl-1-cyano- and 2-aryl-1-fluoronaphthalenes were reacted with N-butyllithium or lithium morpholide to give new benzophen­anthridine derivatives.
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title Synthesis, Cross-Coupling, and Anionic Cyclization of ortho-Substituted Naphthaleneboronic Esters
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