A New Short and Efficient Route to 3-Deoxy-d-manno-oct-2-ulosonic Acid (KDO) and 3-Deoxy-d-arabino-hept-2-ulosonic Acid (DAH)

Abstract An efficient synthesis of lactones 5 and 6, known intermediates towards KDO and DAH, respectively, has been achieved by a short and highly efficient route. Homologation of protected D-mannose and D-arabinose was performed by a Peterson reaction with 2-lithio-2-trimethylsilyldithiane or the...

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Veröffentlicht in:Synthesis (Stuttgart) 2006-04, Vol.2006 (7), p.1200-1204
Hauptverfasser: Kikelj, Vincent, Plantier-Royon, Richard, Portella, Charles
Format: Artikel
Sprache:eng
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