A New Short and Efficient Route to 3-Deoxy-d-manno-oct-2-ulosonic Acid (KDO) and 3-Deoxy-d-arabino-hept-2-ulosonic Acid (DAH)
Abstract An efficient synthesis of lactones 5 and 6, known intermediates towards KDO and DAH, respectively, has been achieved by a short and highly efficient route. Homologation of protected D-mannose and D-arabinose was performed by a Peterson reaction with 2-lithio-2-trimethylsilyldithiane or the...
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Veröffentlicht in: | Synthesis (Stuttgart) 2006-04, Vol.2006 (7), p.1200-1204 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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