Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions

Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In th...

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Veröffentlicht in:Synlett 2005-09, Vol.2005 (14), p.2209-2213
Hauptverfasser: Andersen, Jacob, Madsen, Ulf, Björkling, Fredrik, Liang, Xifu
Format: Artikel
Sprache:eng
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