Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions

Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions

Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In th...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synlett 2005-09, Vol.2005 (14), p.2209-2213
Hauptverfasser: Andersen, Jacob, Madsen, Ulf, Björkling, Fredrik, Liang, Xifu
Format: Artikel
Sprache:eng
Schlagworte:
letter
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2213
container_issue 14
container_start_page 2209
container_title Synlett
container_volume 2005
creator Andersen, Jacob
Madsen, Ulf
Björkling, Fredrik
Liang, Xifu
description Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In the case of aryl iodides, the transformation could be carried out at room temperature.
doi_str_mv 10.1055/s-2005-872248
format Article
fullrecord <record><control><sourceid>thieme_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1055_s_2005_872248</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1055_s_2005_872248</sourcerecordid><originalsourceid>FETCH-LOGICAL-c340t-18569842df0f85711edc8d685e648d3958d6f22c309b039cd42120bdaade41743</originalsourceid><addsrcrecordid>eNp1kMtKAzEUQIMoOFaX7vMBRm9eM8lyKNYKFcHHOkwnCU2ZR0mmi_HrnXbcurrcw-FyOQjdU3ikIOVTIgxAElUwJtQFyqjgxYR0foky0DwnklFxjW5S2gNQoTRkaPVRHYLFn2M37FwKCfcel3FscPkTrEvYx76dwbpqzuTYWRfxW2gsXvadDUPou3SLrnzVJHf3Nxfoe_X8tVyTzfvL67LckJoLGAhVMtdKMOvBK1lQ6mytbK6ky4WyXMtp8YzVHPQWuK6tYJTB1laVdYIWgi8Qme_WsU8pOm8OMbRVHA0Fc4pgkjlFMHOEyX-Y_WEXXOvMvj_GbnrwH_0XeWFcAg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions</title><source>Thieme Connect Journals</source><creator>Andersen, Jacob ; Madsen, Ulf ; Björkling, Fredrik ; Liang, Xifu</creator><creatorcontrib>Andersen, Jacob ; Madsen, Ulf ; Björkling, Fredrik ; Liang, Xifu</creatorcontrib><description>Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In the case of aryl iodides, the transformation could be carried out at room temperature.</description><identifier>ISSN: 0936-5214</identifier><identifier>EISSN: 1437-2096</identifier><identifier>DOI: 10.1055/s-2005-872248</identifier><language>eng</language><subject>letter</subject><ispartof>Synlett, 2005-09, Vol.2005 (14), p.2209-2213</ispartof><rights>Georg Thieme Verlag Stuttgart · New York</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-18569842df0f85711edc8d685e648d3958d6f22c309b039cd42120bdaade41743</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2005-872248.pdf$$EPDF$$P50$$Gthieme$$H</linktopdf><linktohtml>$$Uhttps://www.thieme-connect.de/products/ejournals/html/10.1055/s-2005-872248$$EHTML$$P50$$Gthieme$$H</linktohtml><link.rule.ids>315,781,785,3018,3019,27929,27930,54564,54565</link.rule.ids></links><search><creatorcontrib>Andersen, Jacob</creatorcontrib><creatorcontrib>Madsen, Ulf</creatorcontrib><creatorcontrib>Björkling, Fredrik</creatorcontrib><creatorcontrib>Liang, Xifu</creatorcontrib><title>Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions</title><title>Synlett</title><addtitle>Synlett</addtitle><description>Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In the case of aryl iodides, the transformation could be carried out at room temperature.</description><subject>letter</subject><issn>0936-5214</issn><issn>1437-2096</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKAzEUQIMoOFaX7vMBRm9eM8lyKNYKFcHHOkwnCU2ZR0mmi_HrnXbcurrcw-FyOQjdU3ikIOVTIgxAElUwJtQFyqjgxYR0foky0DwnklFxjW5S2gNQoTRkaPVRHYLFn2M37FwKCfcel3FscPkTrEvYx76dwbpqzuTYWRfxW2gsXvadDUPou3SLrnzVJHf3Nxfoe_X8tVyTzfvL67LckJoLGAhVMtdKMOvBK1lQ6mytbK6ky4WyXMtp8YzVHPQWuK6tYJTB1laVdYIWgi8Qme_WsU8pOm8OMbRVHA0Fc4pgkjlFMHOEyX-Y_WEXXOvMvj_GbnrwH_0XeWFcAg</recordid><startdate>20050902</startdate><enddate>20050902</enddate><creator>Andersen, Jacob</creator><creator>Madsen, Ulf</creator><creator>Björkling, Fredrik</creator><creator>Liang, Xifu</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050902</creationdate><title>Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions</title><author>Andersen, Jacob ; Madsen, Ulf ; Björkling, Fredrik ; Liang, Xifu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-18569842df0f85711edc8d685e648d3958d6f22c309b039cd42120bdaade41743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>letter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Andersen, Jacob</creatorcontrib><creatorcontrib>Madsen, Ulf</creatorcontrib><creatorcontrib>Björkling, Fredrik</creatorcontrib><creatorcontrib>Liang, Xifu</creatorcontrib><collection>CrossRef</collection><jtitle>Synlett</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Andersen, Jacob</au><au>Madsen, Ulf</au><au>Björkling, Fredrik</au><au>Liang, Xifu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions</atitle><jtitle>Synlett</jtitle><addtitle>Synlett</addtitle><date>2005-09-02</date><risdate>2005</risdate><volume>2005</volume><issue>14</issue><spage>2209</spage><epage>2213</epage><pages>2209-2213</pages><issn>0936-5214</issn><eissn>1437-2096</eissn><abstract>Abstract A rapid synthesis of aryl azides from the corresponding aryl halides catalyzed by CuI/diamine is described. Sodium ascorbate was found to have a positive effect on stabilization of the catalyst system. The reactions were performed under very mild conditions generally with high yields. In the case of aryl iodides, the transformation could be carried out at room temperature.</abstract><doi>10.1055/s-2005-872248</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0936-5214
ispartof Synlett, 2005-09, Vol.2005 (14), p.2209-2213
issn 0936-5214
1437-2096
language eng
recordid cdi_crossref_primary_10_1055_s_2005_872248
source Thieme Connect Journals
subjects letter
title Rapid Synthesis of Aryl Azides from Aryl Halides under Mild Conditions
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-12T22%3A00%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-thieme_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rapid%20Synthesis%20of%20Aryl%20Azides%20from%20Aryl%20Halides%20under%20Mild%20Conditions&rft.jtitle=Synlett&rft.au=Andersen,%20Jacob&rft.date=2005-09-02&rft.volume=2005&rft.issue=14&rft.spage=2209&rft.epage=2213&rft.pages=2209-2213&rft.issn=0936-5214&rft.eissn=1437-2096&rft_id=info:doi/10.1055/s-2005-872248&rft_dat=%3Cthieme_cross%3E10_1055_s_2005_872248%3C/thieme_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true