Synthesis of the α,β-Unsaturated δ-Lactones (+)-Anhydrocalopin and (+)-Dehydrocalopin

ABSTRACT During our investigations on the calopin group of mushroom metabolites, a synthesis of 3,4-disubstituted α,β-unsaturated δ-lactones has been developed. It was applied to the synthesis of optically active dehydrocalopin (2) and anhydrocalopin (3).

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Veröffentlicht in:Synthesis (Stuttgart) 2003-01, Vol.1 (1), p.101-106
Hauptverfasser: Ebel, Heiner, Zeitler, Kirsten, Steglich, Wolfgang
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT During our investigations on the calopin group of mushroom metabolites, a synthesis of 3,4-disubstituted α,β-unsaturated δ-lactones has been developed. It was applied to the synthesis of optically active dehydrocalopin (2) and anhydrocalopin (3).
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2003-36269