Asymmetric Synthesis of 1-Aminopentadecane-3,5,7,9,11,13,15-heptols and of 1,15-Diaminopentadecane-3,5,7,9,11,13-hexols and Derivatives

Asymmetric Synthesis of 1-Aminopentadecane-3,5,7,9,11,13,15-heptols and of 1,15-Diaminopentadecane-3,5,7,9,11,13-hexols and Derivatives

Abstract Starting from 2,2′-methylenedifuran, enantiomeri­cally enriched (98%) (3R,5S,7R,9S,11R,13R)- and (3R,5S,7S,9R,11R,13R)-15-amino-5,7,9,11-tetrahydroxy-3,13-bis-(4-methoxybenzoyloxy)pentadec-1-yl) pivalate were prepared as well as (3R,5R,7R,9R,11S,13S)-1,15-diamino-5,7,9,11-tetra­hydroxypenta...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthesis (Stuttgart) 2002-01, Vol.2002 (14 Special Issue)
Hauptverfasser: Gerber-Lemaire, Sandrine, Popowycz, Florence, Glanzmann, Cécile, Vogel, Pierre
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Abstract Starting from 2,2′-methylenedifuran, enantiomeri­cally enriched (98%) (3R,5S,7R,9S,11R,13R)- and (3R,5S,7S,9R,11R,13R)-15-amino-5,7,9,11-tetrahydroxy-3,13-bis-(4-methoxybenzoyloxy)pentadec-1-yl) pivalate were prepared as well as (3R,5R,7R,9R,11S,13S)-1,15-diamino-5,7,9,11-tetra­hydroxypentadeca-3,13-diyl bis(4-methoxybenzoate) and (3R,5S,7S,9S,11R,13S)-1,15-diaminopentadecane-3,5,7,9,11,13-hexol.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2002-34381