Highly Efficient Allylation of Aldehydes and Three-Component Synthesis of Homoallylamines Using Bismuth Triflate Catalyst

Abstract Bismuth triflate catalyzed allylation of a variety of aldehydes and aldimines using allyltributylstannane has been presented. The reaction proceeds rapidly and yields corresponding homoallylic alcohols and homoallylic amines in good yields. The bismuth triflate displays manifold activity ov...

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Veröffentlicht in:	Synlett 2002, Vol.2002 (10), p.1694-1696
Hauptverfasser:	Choudary, Boyapati M., Chidara, Sridhar, Sekhar, Ch. V.
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Sprache:	eng
Schlagworte:	letter
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description	Abstract Bismuth triflate catalyzed allylation of a variety of aldehydes and aldimines using allyltributylstannane has been presented. The reaction proceeds rapidly and yields corresponding homoallylic alcohols and homoallylic amines in good yields. The bismuth triflate displays manifold activity over the La, Yb, and Sc triflates. The catalyst is reused for allylation of aldehydes and aldimines without significant loss of catalytic activity for four cycles.
doi_str_mv	10.1055/s-2002-34239
format	Article
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title	Highly Efficient Allylation of Aldehydes and Three-Component Synthesis of Homoallylamines Using Bismuth Triflate Catalyst
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