Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent

Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent

Abstract Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synlett 2002, Vol.2002 (3), p.525-527
Hauptverfasser: Monenschein, Holger, Brünjes, Marco, Kirschning, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
letter
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 527
container_issue 3
container_start_page 525
container_title Synlett
container_volume 2002
creator Monenschein, Holger
Brünjes, Marco
Kirschning, Andreas
description Abstract Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.
doi_str_mv 10.1055/s-2002-20486
format Article
fullrecord <record><control><sourceid>thieme_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1055_s_2002_20486</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1055_s_2002_20486</sourcerecordid><originalsourceid>FETCH-LOGICAL-c335t-5acbff11291d384079efd6ef827f3376ef3f8a1c976db90cf8697b7ce22b50cd3</originalsourceid><addsrcrecordid>eNptUMtOwzAQtBBIlMKND_CdBvxI4vhYlRaQKpUDcEOW46wVV3kUO0Xt3-NQjlx2ZqTZ1ewgdEvJPSVZ9hASRgiLIy3yMzShKRdRyPwcTYjkeZIxml6iqxC2hNC0kGSCPtduqJ0eoMKProWh7g_HEY5N1Lsaukhe6z7satcB3hxcBTM8xx_ggx5cA3jV-3bcxwvtS925vsPLr7371g10wzW6sLoJcPOHU_S-Wr4tnpP15ullMV8nhvNsSDJtSmspZZJWvEiJkGCrHGzBhOVcRMZtoamRIq9KSYwtcilKYYCxMiOm4lM0O901vg_Bg1U771rtj4oSNVajghqrUb_VRPvdyR5fhxbUtt_7Lub73_0DTQpl7Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent</title><source>Thieme Connect Journals</source><creator>Monenschein, Holger ; Brünjes, Marco ; Kirschning, Andreas</creator><creatorcontrib>Monenschein, Holger ; Brünjes, Marco ; Kirschning, Andreas</creatorcontrib><description>Abstract Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.</description><identifier>ISSN: 0936-5214</identifier><identifier>EISSN: 1437-2096</identifier><identifier>DOI: 10.1055/s-2002-20486</identifier><language>eng</language><subject>letter</subject><ispartof>Synlett, 2002, Vol.2002 (3), p.525-527</ispartof><rights>Georg Thieme Verlag Stuttgart · New York</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c335t-5acbff11291d384079efd6ef827f3376ef3f8a1c976db90cf8697b7ce22b50cd3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2002-20486.pdf$$EPDF$$P50$$Gthieme$$H</linktopdf><linktohtml>$$Uhttps://www.thieme-connect.de/products/ejournals/html/10.1055/s-2002-20486$$EHTML$$P50$$Gthieme$$H</linktohtml><link.rule.ids>314,780,784,3015,3016,4022,27922,27923,27924,54558,54559</link.rule.ids></links><search><creatorcontrib>Monenschein, Holger</creatorcontrib><creatorcontrib>Brünjes, Marco</creatorcontrib><creatorcontrib>Kirschning, Andreas</creatorcontrib><title>Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent</title><title>Synlett</title><addtitle>Synlett</addtitle><description>Abstract Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.</description><subject>letter</subject><issn>0936-5214</issn><issn>1437-2096</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNptUMtOwzAQtBBIlMKND_CdBvxI4vhYlRaQKpUDcEOW46wVV3kUO0Xt3-NQjlx2ZqTZ1ewgdEvJPSVZ9hASRgiLIy3yMzShKRdRyPwcTYjkeZIxml6iqxC2hNC0kGSCPtduqJ0eoMKProWh7g_HEY5N1Lsaukhe6z7satcB3hxcBTM8xx_ggx5cA3jV-3bcxwvtS925vsPLr7371g10wzW6sLoJcPOHU_S-Wr4tnpP15ullMV8nhvNsSDJtSmspZZJWvEiJkGCrHGzBhOVcRMZtoamRIq9KSYwtcilKYYCxMiOm4lM0O901vg_Bg1U771rtj4oSNVajghqrUb_VRPvdyR5fhxbUtt_7Lub73_0DTQpl7Q</recordid><startdate>2002</startdate><enddate>2002</enddate><creator>Monenschein, Holger</creator><creator>Brünjes, Marco</creator><creator>Kirschning, Andreas</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2002</creationdate><title>Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent</title><author>Monenschein, Holger ; Brünjes, Marco ; Kirschning, Andreas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-5acbff11291d384079efd6ef827f3376ef3f8a1c976db90cf8697b7ce22b50cd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>letter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Monenschein, Holger</creatorcontrib><creatorcontrib>Brünjes, Marco</creatorcontrib><creatorcontrib>Kirschning, Andreas</creatorcontrib><collection>CrossRef</collection><jtitle>Synlett</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Monenschein, Holger</au><au>Brünjes, Marco</au><au>Kirschning, Andreas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent</atitle><jtitle>Synlett</jtitle><addtitle>Synlett</addtitle><date>2002</date><risdate>2002</risdate><volume>2002</volume><issue>3</issue><spage>525</spage><epage>527</epage><pages>525-527</pages><issn>0936-5214</issn><eissn>1437-2096</eissn><abstract>Abstract Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.</abstract><doi>10.1055/s-2002-20486</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0936-5214
ispartof Synlett, 2002, Vol.2002 (3), p.525-527
issn 0936-5214
1437-2096
language eng
recordid cdi_crossref_primary_10_1055_s_2002_20486
source Thieme Connect Journals
subjects letter
title Lithiated Dimethoxymethyl Diphenyl Phosphine Oxide, A Versatile Formiate Carbanion Equivalent
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T16%3A23%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-thieme_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Lithiated%20Dimethoxymethyl%20Diphenyl%20Phosphine%20Oxide,%20A%20Versatile%20Formiate%20Carbanion%20Equivalent&rft.jtitle=Synlett&rft.au=Monenschein,%20Holger&rft.date=2002&rft.volume=2002&rft.issue=3&rft.spage=525&rft.epage=527&rft.pages=525-527&rft.issn=0936-5214&rft.eissn=1437-2096&rft_id=info:doi/10.1055/s-2002-20486&rft_dat=%3Cthieme_cross%3E10_1055_s_2002_20486%3C/thieme_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true