Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene

Abstract The intramolecular [2+2] photocycloaddition of α,β-butenolides to a terminal double bond tethered to the lactone through the γ-position and located at a suitable distance has been studied. The regioselectivity of the photoisomerization depends on the substitution pattern of the substrate an...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Synthesis (Stuttgart) 2001-01, Vol.112 (8)
Hauptverfasser:	Busqué, Félix, March, Pedro de, Figueredo, Marta, Font, Josep, Margaretha, Paul, Raya, Javier
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page
container_issue	8
container_start_page
container_title	Synthesis (Stuttgart)
container_volume	112
creator	Busqué, Félix March, Pedro de Figueredo, Marta Font, Josep Margaretha, Paul Raya, Javier
description	Abstract The intramolecular [2+2] photocycloaddition of α,β-butenolides to a terminal double bond tethered to the lactone through the γ-position and located at a suitable distance has been studied. The regioselectivity of the photoisomerization depends on the substitution pattern of the substrate and can be rationalized by simple theoretical calculations performed on the diradical intermediates.
doi_str_mv	10.1055/s-2001-15058
format	Article
fullrecord	<record><control><sourceid>thieme_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1055_s_2001_15058</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1055_s_2001_15058</sourcerecordid><originalsourceid>FETCH-LOGICAL-c269t-ba4a8d65fa54c7bc9e1ee251901392ce35ae7a91fe3015d78b5f1f39c7a2acdc3</originalsourceid><addsrcrecordid>eNptkM1KAzEYRYMoWKs7HyB7G00mTTNZVvGnUFCkgruQZr7Y1MxEklToY-mD9JlsrUtXFy6Hy-UgdM7oJaNCXGVSUcoIE1TUB6jHhlySitHXQ9SjlCsi65odo5Ocl5RSWXHVQ_YZ3nzMEMAW_-nLGkeHywLwpCvJtHHbr4JJ-GkRS7RrG6JpGl987Hbg5muw-SbXqwJdDL6BjEvEBs8gtb4zAY_DO3Rwio6cCRnO_rKPXu5uZzcPZPp4P7kZT4mtRqqQuRmauhkJZ8TQyrlVwAAqwRRlXFUWuDAgjWIOOGWikfVcOOa4stJUxjaW99Fgv2tTzDmB0x_JtyatNaN6J0hnvROkfwVt8Ys9XhYeWtDLuErb0_l_-gfvG2oU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene</title><source>Thieme Connect Journals</source><creator>Busqué, Félix ; March, Pedro de ; Figueredo, Marta ; Font, Josep ; Margaretha, Paul ; Raya, Javier</creator><creatorcontrib>Busqué, Félix ; March, Pedro de ; Figueredo, Marta ; Font, Josep ; Margaretha, Paul ; Raya, Javier</creatorcontrib><description>Abstract The intramolecular [2+2] photocycloaddition of α,β-butenolides to a terminal double bond tethered to the lactone through the γ-position and located at a suitable distance has been studied. The regioselectivity of the photoisomerization depends on the substitution pattern of the substrate and can be rationalized by simple theoretical calculations performed on the diradical intermediates.</description><identifier>ISSN: 0039-7881</identifier><identifier>EISSN: 1437-210X</identifier><identifier>DOI: 10.1055/s-2001-15058</identifier><language>eng</language><ispartof>Synthesis (Stuttgart), 2001-01, Vol.112 (8)</ispartof><rights>Georg Thieme Verlag Stuttgart · New York</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c269t-ba4a8d65fa54c7bc9e1ee251901392ce35ae7a91fe3015d78b5f1f39c7a2acdc3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2001-15058.pdf$$EPDF$$P50$$Gthieme$$H</linktopdf><linktohtml>$$Uhttps://www.thieme-connect.de/products/ejournals/html/10.1055/s-2001-15058$$EHTML$$P50$$Gthieme$$H</linktohtml><link.rule.ids>314,776,780,3004,3005,27901,27902,54534,54535</link.rule.ids></links><search><creatorcontrib>Busqué, Félix</creatorcontrib><creatorcontrib>March, Pedro de</creatorcontrib><creatorcontrib>Figueredo, Marta</creatorcontrib><creatorcontrib>Font, Josep</creatorcontrib><creatorcontrib>Margaretha, Paul</creatorcontrib><creatorcontrib>Raya, Javier</creatorcontrib><title>Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene</title><title>Synthesis (Stuttgart)</title><addtitle>Synthesis</addtitle><description>Abstract The intramolecular [2+2] photocycloaddition of α,β-butenolides to a terminal double bond tethered to the lactone through the γ-position and located at a suitable distance has been studied. The regioselectivity of the photoisomerization depends on the substitution pattern of the substrate and can be rationalized by simple theoretical calculations performed on the diradical intermediates.</description><issn>0039-7881</issn><issn>1437-210X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNptkM1KAzEYRYMoWKs7HyB7G00mTTNZVvGnUFCkgruQZr7Y1MxEklToY-mD9JlsrUtXFy6Hy-UgdM7oJaNCXGVSUcoIE1TUB6jHhlySitHXQ9SjlCsi65odo5Ocl5RSWXHVQ_YZ3nzMEMAW_-nLGkeHywLwpCvJtHHbr4JJ-GkRS7RrG6JpGl987Hbg5muw-SbXqwJdDL6BjEvEBs8gtb4zAY_DO3Rwio6cCRnO_rKPXu5uZzcPZPp4P7kZT4mtRqqQuRmauhkJZ8TQyrlVwAAqwRRlXFUWuDAgjWIOOGWikfVcOOa4stJUxjaW99Fgv2tTzDmB0x_JtyatNaN6J0hnvROkfwVt8Ys9XhYeWtDLuErb0_l_-gfvG2oU</recordid><startdate>20010101</startdate><enddate>20010101</enddate><creator>Busqué, Félix</creator><creator>March, Pedro de</creator><creator>Figueredo, Marta</creator><creator>Font, Josep</creator><creator>Margaretha, Paul</creator><creator>Raya, Javier</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20010101</creationdate><title>Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene</title><author>Busqué, Félix ; March, Pedro de ; Figueredo, Marta ; Font, Josep ; Margaretha, Paul ; Raya, Javier</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c269t-ba4a8d65fa54c7bc9e1ee251901392ce35ae7a91fe3015d78b5f1f39c7a2acdc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Busqué, Félix</creatorcontrib><creatorcontrib>March, Pedro de</creatorcontrib><creatorcontrib>Figueredo, Marta</creatorcontrib><creatorcontrib>Font, Josep</creatorcontrib><creatorcontrib>Margaretha, Paul</creatorcontrib><creatorcontrib>Raya, Javier</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis (Stuttgart)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Busqué, Félix</au><au>March, Pedro de</au><au>Figueredo, Marta</au><au>Font, Josep</au><au>Margaretha, Paul</au><au>Raya, Javier</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene</atitle><jtitle>Synthesis (Stuttgart)</jtitle><addtitle>Synthesis</addtitle><date>2001-01-01</date><risdate>2001</risdate><volume>112</volume><issue>8</issue><issn>0039-7881</issn><eissn>1437-210X</eissn><abstract>Abstract The intramolecular [2+2] photocycloaddition of α,β-butenolides to a terminal double bond tethered to the lactone through the γ-position and located at a suitable distance has been studied. The regioselectivity of the photoisomerization depends on the substitution pattern of the substrate and can be rationalized by simple theoretical calculations performed on the diradical intermediates.</abstract><doi>10.1055/s-2001-15058</doi></addata></record>
fulltext	fulltext
identifier	ISSN: 0039-7881
ispartof	Synthesis (Stuttgart), 2001-01, Vol.112 (8)
issn	0039-7881 1437-210X
language	eng
recordid	cdi_crossref_primary_10_1055_s_2001_15058
source	Thieme Connect Journals
title	Regioselectivity of the Intramolecular Photocycloaddition of α,β-Butenolides to a Terminal Alkene
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T22%3A39%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-thieme_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Regioselectivity%20of%20the%20Intramolecular%20Photocycloaddition%20of%20%CE%B1,%CE%B2-Butenolides%20to%20a%20Terminal%20Alkene&rft.jtitle=Synthesis%20(Stuttgart)&rft.au=Busqu%C3%A9,%20F%C3%A9lix&rft.date=2001-01-01&rft.volume=112&rft.issue=8&rft.issn=0039-7881&rft.eissn=1437-210X&rft_id=info:doi/10.1055/s-2001-15058&rft_dat=%3Cthieme_cross%3E10_1055_s_2001_15058%3C/thieme_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true