Synthesis of Catenanes from a BMP32C10-Based Cryptand Tuned by the Linkage Length of Paraquat Salts

Synthesis of Catenanes from a BMP32C10-Based Cryptand Tuned by the Linkage Length of Paraquat Salts

Abstract A series of catenanes have been synthesized through olefin metathesis from a BMP32C10-based cryptand and paraquat guests attached with two terminal alkenes. Distribution of the catenane products can be significantly affected by the linkage length on the paraquat guests. In the presence of B...

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Veröffentlicht in:Synthesis (Stuttgart) 2021-01, Vol.53 (2), p.338-343
Hauptverfasser: Yan, Feng-Zhi, Shao, Yuan-Guang, Zhang, Zibin, Shen, Yan-Feng, Huang, Xue-Chun, Zhang, Pei-Ling, Li, Shijun
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container_end_page 343
container_issue 2
container_start_page 338
container_title Synthesis (Stuttgart)
container_volume 53
creator Yan, Feng-Zhi
Shao, Yuan-Guang
Zhang, Zibin
Shen, Yan-Feng
Huang, Xue-Chun
Zhang, Pei-Ling
Li, Shijun
description Abstract A series of catenanes have been synthesized through olefin metathesis from a BMP32C10-based cryptand and paraquat guests attached with two terminal alkenes. Distribution of the catenane products can be significantly affected by the linkage length on the paraquat guests. In the presence of BMP32C10-based cryptand, the paraquat salt with a long linkage facilitates intramolecular olefin metathesis to release a [2]catenane as the sole catenation product, while the use of a paraquat salt with a shorter linkage leads to the simultaneous generation of [2]-, [3]-, and [4]-catenanes.
doi_str_mv 10.1055/s-0040-1707290
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title Synthesis of Catenanes from a BMP32C10-Based Cryptand Tuned by the Linkage Length of Paraquat Salts
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