Methyl-α-d-glucopyranoside as Green Ligand for Selective Copper-Catalyzed N-Arylation

Methyl-α-d-glucopyranoside as Green Ligand for Selective Copper-Catalyzed N-Arylation

Abstract In the selective N-arylation of amines or azoles with aryl halides­, methyl-α- d -glucopyranoside ( MG ) was found to function as a green ligand of copper powder. In addition, nitrogen heterocyclic amine compounds can also undergo the N-arylation coupling with heterocyclic aryl chlorides. T...

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Veröffentlicht in:Synthesis (Stuttgart) 2019-12, Vol.51 (24), p.4590-4600
Hauptverfasser: Chen, Yuanguang, Du, Fangyu, Chen, Fengyang, Zhou, Qifan, Chen, Guoliang
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container_end_page 4600
container_issue 24
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container_title Synthesis (Stuttgart)
container_volume 51
creator Chen, Yuanguang
Du, Fangyu
Chen, Fengyang
Zhou, Qifan
Chen, Guoliang
description Abstract In the selective N-arylation of amines or azoles with aryl halides­, methyl-α- d -glucopyranoside ( MG ) was found to function as a green ligand of copper powder. In addition, nitrogen heterocyclic amine compounds can also undergo the N-arylation coupling with heterocyclic aryl chlorides. This process allows access to a variety of aromatic amines and aryl azoles under mild reaction conditions, has good tolerance, and proceeds in moderate to high yield.
doi_str_mv 10.1055/s-0039-1690702
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title Methyl-α-d-glucopyranoside as Green Ligand for Selective Copper-Catalyzed N-Arylation
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