Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst

Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst

Abstract A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthesis (Stuttgart) 2018-01, Vol.50 (1), p.119-126
Hauptverfasser: Ajdačić, Vladimir, Nikolić, Andrea, Simić, Stefan, Manojlović, Dragan, Stojanović, Zoran, Nikodinovic-Runic, Jasmina, Opsenica, Igor M.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 126
container_issue 1
container_start_page 119
container_title Synthesis (Stuttgart)
container_volume 50
creator Ajdačić, Vladimir
Nikolić, Andrea
Simić, Stefan
Manojlović, Dragan
Stojanović, Zoran
Nikodinovic-Runic, Jasmina
Opsenica, Igor M.
description Abstract A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.
doi_str_mv 10.1055/s-0036-1590892
format Article
fullrecord <record><control><sourceid>thieme_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1055_s_0036_1590892</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1055_s_0036_1590892</sourcerecordid><originalsourceid>FETCH-LOGICAL-c317t-d2b320b8f49dd23353ac2c6284de0351a93201bf53d140296eb79adb096eb05e3</originalsourceid><addsrcrecordid>eNp1kE9Lw0AQxRdRsFavnvcLbN0_SZM9llatUFHQgrcwyU6alE227CaHfHsT2oMXTzPD-73h8Qh5FHwheBw_Bca5WjIRa55qeUVmIlIJk4L_XJPZKGmWpKm4JXchHDnniVR6RvoNFuBz1w4Wutq11JV05V0zHgVdWYPVYDBQaA3dYAXWHbD9Aw6WbsHWE7IPdXug73CosKk7ZF_96eR8h4Z-grVg6r6ha-jADqG7Jzcl2IAPlzkn-5fn7_WW7T5e39arHSuUSDpmZK4kz9My0sZIpWIFhSyWMo0MchUL0KMs8jJWRkRc6iXmiQaT82njMao5WZz_Ft6F4LHMTr5uwA-Z4NlUWhayqbTsUtpoYGdDV9XYYHZ0vW_HhP_xv8cxbzw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst</title><source>Thieme Connect Journals</source><creator>Ajdačić, Vladimir ; Nikolić, Andrea ; Simić, Stefan ; Manojlović, Dragan ; Stojanović, Zoran ; Nikodinovic-Runic, Jasmina ; Opsenica, Igor M.</creator><creatorcontrib>Ajdačić, Vladimir ; Nikolić, Andrea ; Simić, Stefan ; Manojlović, Dragan ; Stojanović, Zoran ; Nikodinovic-Runic, Jasmina ; Opsenica, Igor M.</creatorcontrib><description>Abstract A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.</description><identifier>ISSN: 0039-7881</identifier><identifier>EISSN: 1437-210X</identifier><identifier>DOI: 10.1055/s-0036-1590892</identifier><language>eng</language><publisher>Stuttgart · New York: Georg Thieme Verlag</publisher><ispartof>Synthesis (Stuttgart), 2018-01, Vol.50 (1), p.119-126</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c317t-d2b320b8f49dd23353ac2c6284de0351a93201bf53d140296eb79adb096eb05e3</citedby><orcidid>0000-0003-4942-4042</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1590892.pdf$$EPDF$$P50$$Gthieme$$H</linktopdf><linktohtml>$$Uhttps://www.thieme-connect.de/products/ejournals/html/10.1055/s-0036-1590892$$EHTML$$P50$$Gthieme$$H</linktohtml><link.rule.ids>314,780,784,3017,3018,27924,27925,54559,54560</link.rule.ids></links><search><creatorcontrib>Ajdačić, Vladimir</creatorcontrib><creatorcontrib>Nikolić, Andrea</creatorcontrib><creatorcontrib>Simić, Stefan</creatorcontrib><creatorcontrib>Manojlović, Dragan</creatorcontrib><creatorcontrib>Stojanović, Zoran</creatorcontrib><creatorcontrib>Nikodinovic-Runic, Jasmina</creatorcontrib><creatorcontrib>Opsenica, Igor M.</creatorcontrib><title>Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst</title><title>Synthesis (Stuttgart)</title><addtitle>Synthesis</addtitle><description>Abstract A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.</description><issn>0039-7881</issn><issn>1437-210X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFavnvcLbN0_SZM9llatUFHQgrcwyU6alE227CaHfHsT2oMXTzPD-73h8Qh5FHwheBw_Bca5WjIRa55qeUVmIlIJk4L_XJPZKGmWpKm4JXchHDnniVR6RvoNFuBz1w4Wutq11JV05V0zHgVdWYPVYDBQaA3dYAXWHbD9Aw6WbsHWE7IPdXug73CosKk7ZF_96eR8h4Z-grVg6r6ha-jADqG7Jzcl2IAPlzkn-5fn7_WW7T5e39arHSuUSDpmZK4kz9My0sZIpWIFhSyWMo0MchUL0KMs8jJWRkRc6iXmiQaT82njMao5WZz_Ft6F4LHMTr5uwA-Z4NlUWhayqbTsUtpoYGdDV9XYYHZ0vW_HhP_xv8cxbzw</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Ajdačić, Vladimir</creator><creator>Nikolić, Andrea</creator><creator>Simić, Stefan</creator><creator>Manojlović, Dragan</creator><creator>Stojanović, Zoran</creator><creator>Nikodinovic-Runic, Jasmina</creator><creator>Opsenica, Igor M.</creator><general>Georg Thieme Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4942-4042</orcidid></search><sort><creationdate>20180101</creationdate><title>Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst</title><author>Ajdačić, Vladimir ; Nikolić, Andrea ; Simić, Stefan ; Manojlović, Dragan ; Stojanović, Zoran ; Nikodinovic-Runic, Jasmina ; Opsenica, Igor M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c317t-d2b320b8f49dd23353ac2c6284de0351a93201bf53d140296eb79adb096eb05e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ajdačić, Vladimir</creatorcontrib><creatorcontrib>Nikolić, Andrea</creatorcontrib><creatorcontrib>Simić, Stefan</creatorcontrib><creatorcontrib>Manojlović, Dragan</creatorcontrib><creatorcontrib>Stojanović, Zoran</creatorcontrib><creatorcontrib>Nikodinovic-Runic, Jasmina</creatorcontrib><creatorcontrib>Opsenica, Igor M.</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis (Stuttgart)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ajdačić, Vladimir</au><au>Nikolić, Andrea</au><au>Simić, Stefan</au><au>Manojlović, Dragan</au><au>Stojanović, Zoran</au><au>Nikodinovic-Runic, Jasmina</au><au>Opsenica, Igor M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst</atitle><jtitle>Synthesis (Stuttgart)</jtitle><addtitle>Synthesis</addtitle><date>2018-01-01</date><risdate>2018</risdate><volume>50</volume><issue>1</issue><spage>119</spage><epage>126</epage><pages>119-126</pages><issn>0039-7881</issn><eissn>1437-210X</eissn><abstract>Abstract A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.</abstract><cop>Stuttgart · New York</cop><pub>Georg Thieme Verlag</pub><doi>10.1055/s-0036-1590892</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-4942-4042</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0039-7881
ispartof Synthesis (Stuttgart), 2018-01, Vol.50 (1), p.119-126
issn 0039-7881
1437-210X
language eng
recordid cdi_crossref_primary_10_1055_s_0036_1590892
source Thieme Connect Journals
title Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T12%3A11%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-thieme_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Decarbonylation%20of%20Aromatic%20Aldehydes%20and%20Dehalogenation%20of%20Aryl%20Halides%20Using%20Maghemite-Supported%20Palladium%20Catalyst&rft.jtitle=Synthesis%20(Stuttgart)&rft.au=Ajda%C4%8Di%C4%87,%20Vladimir&rft.date=2018-01-01&rft.volume=50&rft.issue=1&rft.spage=119&rft.epage=126&rft.pages=119-126&rft.issn=0039-7881&rft.eissn=1437-210X&rft_id=info:doi/10.1055/s-0036-1590892&rft_dat=%3Cthieme_cross%3E10_1055_s_0036_1590892%3C/thieme_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true