Recent Advances in Dual Visible Light Photoredox and Gold-Catalyzed Reactions
Abstract In a dual visible light photoredox and gold catalysis system, Au(I) is oxidized in a stepwise fashion by photogenerated aryl radicals leading to cationic Au(III) species, a process which is incorporated into various domino functionalization/coupling reactions. This article presents an overv...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2016-12, Vol.49 (6), p.1150-1157 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
In a dual visible light photoredox and gold catalysis system, Au(I) is oxidized in a stepwise fashion by photogenerated aryl radicals leading to cationic Au(III) species, a process which is incorporated into various domino functionalization/coupling reactions. This article presents an overview of the major contributions reported in this field, emphasizing those involving aryldiazonium or diaryliodonium salts as general radical sources.
1 Introduction
2 Domino Nucleophilic Addition/Arylation
3 Domino Rearrangement/Arylation
4 Cross-Coupling
5 Conclusion |
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| ISSN: | 0039-7881 1437-210X |
| DOI: | 10.1055/s-0036-1588365 |