Trifluoroborane-Catalyzed C–H Functionalization/S–H Insertion Reaction: Construction of N,S-Acetal Quaternary Centers

Abstract The trifluoroborane-catalyzed C–H functionalization/S–H insertion reaction of α-diazophosphonates with thiols has been developed. A plausible reaction mechanism has been proposed to understand the combined reaction. This process provides straightforward access to N , S -acetals containing q...

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Veröffentlicht in:	Synthesis (Stuttgart) 2015-06, Vol.47 (11), p.1669-1677
Hauptverfasser:	Cai, Yan, Ge, Haihong, Sun, Weize, Miao, Zhiwei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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