The First Stereoselective Synthesis of a Dithiane Derivative of the C18 β-Diketodiene System Proposed for an Active Compound Isolated from Cantharellus cibarius (Chanterelle)

Abstract A stereocontrolled synthesis of a thioketal system that is a direct precursor of an active compound isolated from chanterelle was accomplished by using readily available methyl 11-[2-(2-oxoethyl)-1,3-dithian-2-yl]undec-9-ynoate as a key intermediate. The synthesis involves simple and straig...

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Veröffentlicht in:Synthesis (Stuttgart) 2015-04, Vol.47 (8), p.1181-1189
Hauptverfasser: Grodner, Jacek, Gołębiewski, W. Marek, Willis, Michael C., Osborne, James D., Gucma, Mirosław
Format: Artikel
Sprache:eng
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