Total Synthesis of Atisane-Type Diterpenoids and Related Diterpenoid Alkaloids
Abstract Atisane-type compounds and related natural products are attractive for their molecular skeletons and pharmaceutical bioactivities. This review summarizes total syntheses of atisane-type diterpenoids and related diterpenoid alkaloids. 1 Introduction 2 Total Synthesis and Synthetic Studies of...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2015-09, Vol.47 (18), p.2691-2708 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
Atisane-type compounds and related natural products are attractive for their molecular skeletons and pharmaceutical bioactivities. This review summarizes total syntheses of atisane-type diterpenoids and related diterpenoid alkaloids.
1 Introduction
2 Total Synthesis and Synthetic Studies of Atisane-Type Diterpenoids and Related Diterpenoid Alkaloids
2.1 Ionic Methods
2.1.1 S
N
2 Substitution Reaction
2.1.2 Aldol Reaction
2.1.3 Intramolecular Double Michael Addition
2.2 Free-Radical Methods
2.2.1 Free-Radical Rearrangement
2.2.2 Free-Radical Addition
2.3 Diels–Alder Cycloaddition
3 Conclusion |
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| ISSN: | 0039-7881 1437-210X |
| DOI: | 10.1055/s-0034-1378743 |