Efficient Multigram Syntheses of Air-Stable, Fluorescent Primary Phosphines via Palladium-Catalyzed Phosphonylation of Aryl Bromides

Abstract Air-stable, fluorescent primary phosphines have been prepared on a multigram scale. The two key synthetic steps are an optimized palladium-catalyzed phosphonylation of aryl bromides and a boron–carbon bond formation reaction. The method provides a valuable synthetic route to novel fluoresce...

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Veröffentlicht in:	Synthesis (Stuttgart) 2014-10, Vol.46 (19), p.2622-2628
Hauptverfasser:	Davies, Laura H., Wallis, Jennifer F., Probert, Michael R., Higham, Lee J.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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