Synthesis of Cyclobutanes and Cyclobutenes by Strain-Release-Driven Ring-Opening of Bicyclo[1.1.0]butanes
Cyclobutanes and cyclobutenes exhibit intriguing structures and demonstrate significant biological activities and diverse synthetic applications. This review aims to summarize recent progress in strain-release-driven ring-opening reactions of bicyclo[1.1.0]butanes (BCBs) to synthesize these four-mem...
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| creator | Zhan, Xuan He, Heng-Xian Peng, Quanxin Feng, Jian-Jun |
| description | Cyclobutanes and cyclobutenes exhibit intriguing structures and demonstrate significant biological activities and diverse synthetic applications. This review aims to summarize recent progress in strain-release-driven ring-opening reactions of bicyclo[1.1.0]butanes (BCBs) to synthesize these four-membered carbon rings. It outlines the strategies, regio- and stereoselectivity, the synthetic scope of reactions, and the mechanistic implications of the catalytic ring-opening process, providing a supplementary perspective to existing reviews.
1 Introduction
2 Thermally Driven Nucleophilic Ring-Opening
3 Thermally Driven Rearrangement and Isomerization Reaction
4 Light-Driven Ring-Opening
5 Transition-Metal/Lewis Acid Catalyzed Ring-Opening
6 Conclusion and Outlook |
| doi_str_mv | 10.1055/a-2402-6920 |
| format | Article |
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1 Introduction
2 Thermally Driven Nucleophilic Ring-Opening
3 Thermally Driven Rearrangement and Isomerization Reaction
4 Light-Driven Ring-Opening
5 Transition-Metal/Lewis Acid Catalyzed Ring-Opening
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1 Introduction
2 Thermally Driven Nucleophilic Ring-Opening
3 Thermally Driven Rearrangement and Isomerization Reaction
4 Light-Driven Ring-Opening
5 Transition-Metal/Lewis Acid Catalyzed Ring-Opening
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1 Introduction
2 Thermally Driven Nucleophilic Ring-Opening
3 Thermally Driven Rearrangement and Isomerization Reaction
4 Light-Driven Ring-Opening
5 Transition-Metal/Lewis Acid Catalyzed Ring-Opening
6 Conclusion and Outlook</abstract><doi>10.1055/a-2402-6920</doi><orcidid>https://orcid.org/0009-0000-4575-148X</orcidid><orcidid>https://orcid.org/0009-0009-5402-9283</orcidid><orcidid>https://orcid.org/0000-0002-6094-3268</orcidid></addata></record> |
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| source | Thieme Connect Journals |
| title | Synthesis of Cyclobutanes and Cyclobutenes by Strain-Release-Driven Ring-Opening of Bicyclo[1.1.0]butanes |
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