Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines

Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines

A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines...

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Veröffentlicht in:Synthesis (Stuttgart) 2024-11, Vol.56 (22), p.3512-3518
Hauptverfasser: Tang, You-Hui, Chen, Peng, Yin, Jin, Shi, Jianghuan, Jiang, Yi-Jun
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container_issue 22
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container_title Synthesis (Stuttgart)
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creator Tang, You-Hui
Chen, Peng
Yin, Jin
Shi, Jianghuan
Jiang, Yi-Jun
description A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.
doi_str_mv 10.1055/a-2378-4540
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title Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines
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