Application of mass spectrometric isotope dilution methodology for 90Sr age-dating with measurements by thermal-ionization and inductively coupled-plasma mass spectrometry
Application of an isotope-dilution method for determining 90 Zr and 90 Sr in a 90 Sr source material spiked with 86 Sr and 92 Zr is described. A miniature gas pressurized extraction chromatography (GPEC) system with a column containing Eichrom Sr Resin™ was used for separating the elements so isobar...
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| Veröffentlicht in: | Journal of analytical atomic spectrometry 2013-08, Vol.28 (9), p.1493-157 |
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| container_title | Journal of analytical atomic spectrometry |
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| creator | Steeb, J. L Graczyk, D. G Tsai, Y Mertz, C. J Essling, A. M Sullivan, V. S Carney, K. P Finck, M. R Giglio, J. J Chamberlain, D. B |
| description | Application of an isotope-dilution method for determining
90
Zr and
90
Sr in a
90
Sr source material spiked with
86
Sr and
92
Zr is described. A miniature gas pressurized extraction chromatography (GPEC) system with a column containing Eichrom Sr Resin™ was used for separating the elements so isobaric isotopes could be measured by mass spectrometry. Zirconium was rinsed through the column with 3 M HNO
3
/trace HF and strontium was eluted with 1% acetic acid. Two mass spectrometric techniques, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry (TIMS), were used for measuring isotope ratios. Data were obtained with
90
Sr from a blood-irradiator source. Results from the TIMS measurements gave a decay time of 45.16 ± 0.26 years, and those from the ICP-MS gave 45.24 ± 0.20 years (uncertainties are expanded uncertainty,
k
= 2). Quadrupole ICP-MS is preferable to TIMS in this application if the ICP-MS data are suitably corrected for non-linearity and mass discrimination.
ICP-QMS is preferable to TIMS in this application if the ICP-QMS data are corrected for non-linearity and mass discrimination. |
| doi_str_mv | 10.1039/c3ja50136a |
| format | Article |
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90
Zr and
90
Sr in a
90
Sr source material spiked with
86
Sr and
92
Zr is described. A miniature gas pressurized extraction chromatography (GPEC) system with a column containing Eichrom Sr Resin™ was used for separating the elements so isobaric isotopes could be measured by mass spectrometry. Zirconium was rinsed through the column with 3 M HNO
3
/trace HF and strontium was eluted with 1% acetic acid. Two mass spectrometric techniques, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry (TIMS), were used for measuring isotope ratios. Data were obtained with
90
Sr from a blood-irradiator source. Results from the TIMS measurements gave a decay time of 45.16 ± 0.26 years, and those from the ICP-MS gave 45.24 ± 0.20 years (uncertainties are expanded uncertainty,
k
= 2). Quadrupole ICP-MS is preferable to TIMS in this application if the ICP-MS data are suitably corrected for non-linearity and mass discrimination.
ICP-QMS is preferable to TIMS in this application if the ICP-QMS data are corrected for non-linearity and mass discrimination.</description><identifier>ISSN: 0267-9477</identifier><identifier>EISSN: 1364-5544</identifier><identifier>DOI: 10.1039/c3ja50136a</identifier><language>eng</language><ispartof>Journal of analytical atomic spectrometry, 2013-08, Vol.28 (9), p.1493-157</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c124f-bcb4c817f2a3985530ce9cb0c0e489c582bcb9c29a07ea8c3c3f1f3b6b16aaaf3</citedby><cites>FETCH-LOGICAL-c124f-bcb4c817f2a3985530ce9cb0c0e489c582bcb9c29a07ea8c3c3f1f3b6b16aaaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Steeb, J. L</creatorcontrib><creatorcontrib>Graczyk, D. G</creatorcontrib><creatorcontrib>Tsai, Y</creatorcontrib><creatorcontrib>Mertz, C. J</creatorcontrib><creatorcontrib>Essling, A. M</creatorcontrib><creatorcontrib>Sullivan, V. S</creatorcontrib><creatorcontrib>Carney, K. P</creatorcontrib><creatorcontrib>Finck, M. R</creatorcontrib><creatorcontrib>Giglio, J. J</creatorcontrib><creatorcontrib>Chamberlain, D. B</creatorcontrib><title>Application of mass spectrometric isotope dilution methodology for 90Sr age-dating with measurements by thermal-ionization and inductively coupled-plasma mass spectrometry</title><title>Journal of analytical atomic spectrometry</title><description>Application of an isotope-dilution method for determining
90
Zr and
90
Sr in a
90
Sr source material spiked with
86
Sr and
92
Zr is described. A miniature gas pressurized extraction chromatography (GPEC) system with a column containing Eichrom Sr Resin™ was used for separating the elements so isobaric isotopes could be measured by mass spectrometry. Zirconium was rinsed through the column with 3 M HNO
3
/trace HF and strontium was eluted with 1% acetic acid. Two mass spectrometric techniques, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry (TIMS), were used for measuring isotope ratios. Data were obtained with
90
Sr from a blood-irradiator source. Results from the TIMS measurements gave a decay time of 45.16 ± 0.26 years, and those from the ICP-MS gave 45.24 ± 0.20 years (uncertainties are expanded uncertainty,
k
= 2). Quadrupole ICP-MS is preferable to TIMS in this application if the ICP-MS data are suitably corrected for non-linearity and mass discrimination.
ICP-QMS is preferable to TIMS in this application if the ICP-QMS data are corrected for non-linearity and mass discrimination.</description><issn>0267-9477</issn><issn>1364-5544</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOD427oW4FaJJk76Ww-ALBlyo63J7m8xkaJuStEr9S_5JqyOKCK4OnPNx7uUQciL4heAyv0S5gZgLmcAOmU2iWBwrtUtmPEpSlqs03ScHIWw45yqO4hl5m3ddbRF661rqDG0gBBo6jb13je69RWqD612naWXr4ROb_LWrXO1WIzXO05w_eAorzaqppl3RF9uvJwjC4HWj2z7QcqT9WvsGajYV2NftOWgrattqwN4-63qk6Iau1hXraggN_HllPCJ7Buqgj7_0kDxdXz0ubtny_uZuMV8yFJEyrMRSYSZSE4HMsziWHHWOJUeuVZZjnEUTkWOUA081ZChRGmFkmZQiAQAjD8n5the9C8FrU3TeNuDHQvDiY-biZ-YJPt3CPuA39ys_-y8vusrId08UjLY</recordid><startdate>20130807</startdate><enddate>20130807</enddate><creator>Steeb, J. L</creator><creator>Graczyk, D. G</creator><creator>Tsai, Y</creator><creator>Mertz, C. J</creator><creator>Essling, A. M</creator><creator>Sullivan, V. S</creator><creator>Carney, K. P</creator><creator>Finck, M. R</creator><creator>Giglio, J. J</creator><creator>Chamberlain, D. B</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130807</creationdate><title>Application of mass spectrometric isotope dilution methodology for 90Sr age-dating with measurements by thermal-ionization and inductively coupled-plasma mass spectrometry</title><author>Steeb, J. L ; Graczyk, D. G ; Tsai, Y ; Mertz, C. J ; Essling, A. M ; Sullivan, V. S ; Carney, K. P ; Finck, M. R ; Giglio, J. J ; Chamberlain, D. B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c124f-bcb4c817f2a3985530ce9cb0c0e489c582bcb9c29a07ea8c3c3f1f3b6b16aaaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Steeb, J. L</creatorcontrib><creatorcontrib>Graczyk, D. G</creatorcontrib><creatorcontrib>Tsai, Y</creatorcontrib><creatorcontrib>Mertz, C. J</creatorcontrib><creatorcontrib>Essling, A. M</creatorcontrib><creatorcontrib>Sullivan, V. S</creatorcontrib><creatorcontrib>Carney, K. P</creatorcontrib><creatorcontrib>Finck, M. R</creatorcontrib><creatorcontrib>Giglio, J. J</creatorcontrib><creatorcontrib>Chamberlain, D. B</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of analytical atomic spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Steeb, J. L</au><au>Graczyk, D. G</au><au>Tsai, Y</au><au>Mertz, C. J</au><au>Essling, A. M</au><au>Sullivan, V. S</au><au>Carney, K. P</au><au>Finck, M. R</au><au>Giglio, J. J</au><au>Chamberlain, D. B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of mass spectrometric isotope dilution methodology for 90Sr age-dating with measurements by thermal-ionization and inductively coupled-plasma mass spectrometry</atitle><jtitle>Journal of analytical atomic spectrometry</jtitle><date>2013-08-07</date><risdate>2013</risdate><volume>28</volume><issue>9</issue><spage>1493</spage><epage>157</epage><pages>1493-157</pages><issn>0267-9477</issn><eissn>1364-5544</eissn><abstract>Application of an isotope-dilution method for determining
90
Zr and
90
Sr in a
90
Sr source material spiked with
86
Sr and
92
Zr is described. A miniature gas pressurized extraction chromatography (GPEC) system with a column containing Eichrom Sr Resin™ was used for separating the elements so isobaric isotopes could be measured by mass spectrometry. Zirconium was rinsed through the column with 3 M HNO
3
/trace HF and strontium was eluted with 1% acetic acid. Two mass spectrometric techniques, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry (TIMS), were used for measuring isotope ratios. Data were obtained with
90
Sr from a blood-irradiator source. Results from the TIMS measurements gave a decay time of 45.16 ± 0.26 years, and those from the ICP-MS gave 45.24 ± 0.20 years (uncertainties are expanded uncertainty,
k
= 2). Quadrupole ICP-MS is preferable to TIMS in this application if the ICP-MS data are suitably corrected for non-linearity and mass discrimination.
ICP-QMS is preferable to TIMS in this application if the ICP-QMS data are corrected for non-linearity and mass discrimination.</abstract><doi>10.1039/c3ja50136a</doi><tpages>15</tpages></addata></record> |
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| ispartof | Journal of analytical atomic spectrometry, 2013-08, Vol.28 (9), p.1493-157 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_c3ja50136a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Application of mass spectrometric isotope dilution methodology for 90Sr age-dating with measurements by thermal-ionization and inductively coupled-plasma mass spectrometry |
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