Cross-linking of ROMP derived polymers using the two-photon induced thiol-ene reaction: towards the fabrication of 3D-polymer microstructures
Ring opening metathesis polymerization (ROMP) has become an important tool for the synthesis of highly defined polymers and various polymer architectures. In the present work, the residual double bonds in ROMP derived polymeric materials were exploited for a photoinduced thiol-ene reaction in order...
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| Veröffentlicht in: | Polymer chemistry 2013-01, Vol.4 (5), p.178-1714 |
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| container_title | Polymer chemistry |
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| creator | Griesser, Thomas Wolfberger, Archim Daschiel, Ute Schmidt, Volker Fian, Alexander Jerrar, Abdellatif Teichert, Christian Kern, Wolfgang |
| description | Ring opening metathesis polymerization (ROMP) has become an important tool for the synthesis of highly defined polymers and various polymer architectures. In the present work, the residual double bonds in ROMP derived polymeric materials were exploited for a photoinduced thiol-ene reaction in order to achieve a selective cross-linking of the macromolecules. Besides the photoinduced thiol-ene reaction, which was investigated by means of FT-IR measurements, also the resulting change in the refractive index was studied by spectroscopic ellipsometry. To demonstrate the versatility of this reaction for the realization of 3D polymeric microstructures, films of poly(norbornene dicarboxylic acid, dimethylester) were structured
via
two-photon induced cross-linking. The accessibility and reactivity of the polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.
The accessibility and reactivity of polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures. |
| doi_str_mv | 10.1039/c2py21002a |
| format | Article |
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via
two-photon induced cross-linking. The accessibility and reactivity of the polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.
The accessibility and reactivity of polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/c2py21002a</identifier><language>eng</language><subject>Crosslinking ; Macromolecules ; Microstructure ; Polymerization ; Polymers ; Ring opening ; Three dimensional</subject><ispartof>Polymer chemistry, 2013-01, Vol.4 (5), p.178-1714</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-f8bf0b04b0b79456ea4719c3c982fa4b4388804aa93a1591d8dc6db337bf21dd3</citedby><cites>FETCH-LOGICAL-c378t-f8bf0b04b0b79456ea4719c3c982fa4b4388804aa93a1591d8dc6db337bf21dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Griesser, Thomas</creatorcontrib><creatorcontrib>Wolfberger, Archim</creatorcontrib><creatorcontrib>Daschiel, Ute</creatorcontrib><creatorcontrib>Schmidt, Volker</creatorcontrib><creatorcontrib>Fian, Alexander</creatorcontrib><creatorcontrib>Jerrar, Abdellatif</creatorcontrib><creatorcontrib>Teichert, Christian</creatorcontrib><creatorcontrib>Kern, Wolfgang</creatorcontrib><title>Cross-linking of ROMP derived polymers using the two-photon induced thiol-ene reaction: towards the fabrication of 3D-polymer microstructures</title><title>Polymer chemistry</title><description>Ring opening metathesis polymerization (ROMP) has become an important tool for the synthesis of highly defined polymers and various polymer architectures. In the present work, the residual double bonds in ROMP derived polymeric materials were exploited for a photoinduced thiol-ene reaction in order to achieve a selective cross-linking of the macromolecules. Besides the photoinduced thiol-ene reaction, which was investigated by means of FT-IR measurements, also the resulting change in the refractive index was studied by spectroscopic ellipsometry. To demonstrate the versatility of this reaction for the realization of 3D polymeric microstructures, films of poly(norbornene dicarboxylic acid, dimethylester) were structured
via
two-photon induced cross-linking. The accessibility and reactivity of the polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.
The accessibility and reactivity of polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.</description><subject>Crosslinking</subject><subject>Macromolecules</subject><subject>Microstructure</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Ring opening</subject><subject>Three dimensional</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYsoOIyzcS_EnQjRpEkfcSfjE0ZGRNclzcOJtk1NUof5Ef5nW2cYcePd3Avnu_dcThQdYnSGEWHnIm5XMUYo5jvRCGcJg4yl8e52Tuh-NPH-DfVFMI1JOoq-ps56DyvTvJvmFVgNnuYPj0AqZz6VBK2tVrVyHnR-kMNCgbC0sF3YYBtgGtmJngoLYyuoGgWc4iIY21yAYJfcSf-zonnpjOCDMDiQK7i5C2ojev_gOhE6p_xBtKd55dVk08fRy8318_QOzua399PLGRQkywPUealRiWiJyozRJFWcZpgJIlgea05LSvI8R5RzRjhOGJa5FKksCclKHWMpyTg6Wd9tnf3olA9FbbxQVcUbZTtfYIKTNGWI0B49XaPDo94pXbTO1NytCoyKIfbiN_YePlrDzost90c__k8vWqnJN0r6jcU</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Griesser, Thomas</creator><creator>Wolfberger, Archim</creator><creator>Daschiel, Ute</creator><creator>Schmidt, Volker</creator><creator>Fian, Alexander</creator><creator>Jerrar, Abdellatif</creator><creator>Teichert, Christian</creator><creator>Kern, Wolfgang</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130101</creationdate><title>Cross-linking of ROMP derived polymers using the two-photon induced thiol-ene reaction: towards the fabrication of 3D-polymer microstructures</title><author>Griesser, Thomas ; Wolfberger, Archim ; Daschiel, Ute ; Schmidt, Volker ; Fian, Alexander ; Jerrar, Abdellatif ; Teichert, Christian ; Kern, Wolfgang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-f8bf0b04b0b79456ea4719c3c982fa4b4388804aa93a1591d8dc6db337bf21dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Crosslinking</topic><topic>Macromolecules</topic><topic>Microstructure</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Ring opening</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Griesser, Thomas</creatorcontrib><creatorcontrib>Wolfberger, Archim</creatorcontrib><creatorcontrib>Daschiel, Ute</creatorcontrib><creatorcontrib>Schmidt, Volker</creatorcontrib><creatorcontrib>Fian, Alexander</creatorcontrib><creatorcontrib>Jerrar, Abdellatif</creatorcontrib><creatorcontrib>Teichert, Christian</creatorcontrib><creatorcontrib>Kern, Wolfgang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Griesser, Thomas</au><au>Wolfberger, Archim</au><au>Daschiel, Ute</au><au>Schmidt, Volker</au><au>Fian, Alexander</au><au>Jerrar, Abdellatif</au><au>Teichert, Christian</au><au>Kern, Wolfgang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cross-linking of ROMP derived polymers using the two-photon induced thiol-ene reaction: towards the fabrication of 3D-polymer microstructures</atitle><jtitle>Polymer chemistry</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>4</volume><issue>5</issue><spage>178</spage><epage>1714</epage><pages>178-1714</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>Ring opening metathesis polymerization (ROMP) has become an important tool for the synthesis of highly defined polymers and various polymer architectures. In the present work, the residual double bonds in ROMP derived polymeric materials were exploited for a photoinduced thiol-ene reaction in order to achieve a selective cross-linking of the macromolecules. Besides the photoinduced thiol-ene reaction, which was investigated by means of FT-IR measurements, also the resulting change in the refractive index was studied by spectroscopic ellipsometry. To demonstrate the versatility of this reaction for the realization of 3D polymeric microstructures, films of poly(norbornene dicarboxylic acid, dimethylester) were structured
via
two-photon induced cross-linking. The accessibility and reactivity of the polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.
The accessibility and reactivity of polynorbornene main chain C&z.dbd;C double bonds in the thiol-ene reaction pave the way towards novel strategies for the realization of polymer 3D microstructures.</abstract><doi>10.1039/c2py21002a</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2013-01, Vol.4 (5), p.178-1714 |
| issn | 1759-9954 1759-9962 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_c2py21002a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crosslinking Macromolecules Microstructure Polymerization Polymers Ring opening Three dimensional |
| title | Cross-linking of ROMP derived polymers using the two-photon induced thiol-ene reaction: towards the fabrication of 3D-polymer microstructures |
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