Kinetics, mechanism, and thermochemistry of the gas-phase reaction of atomic chlorine with pyridine

A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of atomic chlorine with pyridine (C(5)H(5)N) as a function of temperature (215-435 K) and pressure (25-250 Torr) in nitrogen bath gas. At T> or = 299 K, measured rate coefficients are...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2007-08, Vol.9 (31), p.4383
Hauptverfasser:	Zhao, Z, Huskey, D T, Olsen, K J, Nicovich, J M, McKee, M L, Wine, P H
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry, Physical - methods Chlorine - chemistry Chlorine Compounds - chemistry Hot Temperature Hydrogen - chemistry Kinetics Models, Chemical Models, Theoretical Molecular Structure Photolysis Pressure Pyridines - chemistry Temperature Thermodynamics Time Factors
Online-Zugang:	Volltext
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