Oxidation of cyclic hydrocarbons by cobalt( III ) acetate
The oxidation of cyclic alkanes and alkenes by cobalt(III) acetate leads to the formation of cycloalkyl and cycloalkenyl acetates. The formation of chlorinated hydrocarbons is observed for cycloalkanes in the presence of carbon tetrachloride but no incorporation of chlorine takes place in the olefin...
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| Veröffentlicht in: | J. Chem. Soc., Perkin Trans. 2 Perkin Trans. 2, 1976 (12), p.1285-1288 |
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| container_end_page | 1288 |
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| container_issue | 12 |
| container_start_page | 1285 |
| container_title | J. Chem. Soc., Perkin Trans. 2 |
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| creator | Verstraelen, Leon Lalmand, Maurice Hubert, André J. Teyssié, Philippe |
| description | The oxidation of cyclic alkanes and alkenes by cobalt(III) acetate leads to the formation of cycloalkyl and cycloalkenyl acetates. The formation of chlorinated hydrocarbons is observed for cycloalkanes in the presence of carbon tetrachloride but no incorporation of chlorine takes place in the olefins. The results are best interpreted by assuming a determining role by both steric and conformational effects on the reaction, involving the conversion of a co-ordinated radical to a carbocation. |
| doi_str_mv | 10.1039/P29760001285 |
| format | Article |
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The formation of chlorinated hydrocarbons is observed for cycloalkanes in the presence of carbon tetrachloride but no incorporation of chlorine takes place in the olefins. The results are best interpreted by assuming a determining role by both steric and conformational effects on the reaction, involving the conversion of a co-ordinated radical to a carbocation.</description><identifier>ISSN: 0300-9580</identifier><identifier>ISSN: 1472-779X</identifier><identifier>EISSN: 1364-5471</identifier><identifier>DOI: 10.1039/P29760001285</identifier><language>eng</language><publisher>Royal Society of Chemistry</publisher><subject>Chemistry ; Chimie ; Physical, chemical, mathematical & earth Sciences ; Physique, chimie, mathématiques & sciences de la terre</subject><ispartof>J. Chem. 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The formation of chlorinated hydrocarbons is observed for cycloalkanes in the presence of carbon tetrachloride but no incorporation of chlorine takes place in the olefins. 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| fulltext | fulltext |
| identifier | ISSN: 0300-9580 |
| ispartof | J. Chem. Soc., Perkin Trans. 2, 1976 (12), p.1285-1288 |
| issn | 0300-9580 1472-779X 1364-5471 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_P29760001285 |
| source | Royal Society of Chemistry Journals Archive (1841-2007) |
| subjects | Chemistry Chimie Physical, chemical, mathematical & earth Sciences Physique, chimie, mathématiques & sciences de la terre |
| title | Oxidation of cyclic hydrocarbons by cobalt( III ) acetate |
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