Multi-functional self-healing polyurethane elastomer based on chair conformation for strain sensors

To address the diverse and complex application environments encountered today, the performance requirements for flexible sensing materials have become increasingly stringent. Traditional flexible sensing materials, which typically possess only excellent mechanical properties, can no longer meet thes...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2024-10, Vol.12 (42), p.28716-2873
Hauptverfasser: Zhu, Yiyao, He, Yuting, Lu, Wentong, Tian, Hao, Fei, Fan, Zhou, Peilong, Wang, Jincheng
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container_issue 42
container_start_page 28716
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 12
creator Zhu, Yiyao
He, Yuting
Lu, Wentong
Tian, Hao
Fei, Fan
Zhou, Peilong
Wang, Jincheng
description To address the diverse and complex application environments encountered today, the performance requirements for flexible sensing materials have become increasingly stringent. Traditional flexible sensing materials, which typically possess only excellent mechanical properties, can no longer meet these demands. We now seek materials that exhibit a range of additional features, including self-healing capabilities, biodegradability and good biocompatibility, to enhance the overall functionality and versatility of flexible sensors. This study successfully synthesized poly(carbonate-chair cyclohexane-urethane) (PCCU) with stable mechanical properties by incorporating a chair conformation structure and dynamic disulfide bonds into the polyurethane backbone. The resulting material demonstrated self-healing capability, antibacterial properties, recyclability, degradability, and biocompatibility. The chair conformation enhanced the material's fatigue resistance and promoted molecular chain mobility, thereby facilitating self-repairing properties. The synthesized polyurethane exhibited high tensile strength (15.09 MPa), high elongation at break (910%), a self-repairing efficiency of 92.75%, low dissipation efficiency (38.46%), 25% mass reduction after 8 weeks of degradation, and efficient antibacterial activity against Staphylococcus aureus and Escherichia coli (92.34% and 88.41%, respectively), with no cytotoxic effects observed. Finally, the polyurethane was encapsulated with conductive ink to validate its sensing capabilities through motion monitoring. This multifunctional polyurethane elastomer enhances the functionality of flexible electronic sensing materials and demonstrates potential applications across multiple domains. This study introduces a polyurethane urea-based flexible sensor material with self-healing, antibacterial, degradable and biocompatible properties. Its multifunctionality makes it ideal for sustainable wearable electronics.
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source Royal Society of Chemistry Free Journals plus Gold OA Content
subjects Antibacterial activity
Biocompatibility
Biodegradability
Biodegradation
Chain mobility
Chemical synthesis
Conformation
Cyclohexane
Cytotoxicity
Degradability
Disulfide bonds
E coli
Elastomers
Fatigue strength
Flexible components
Mechanical properties
Molecular chains
Molecular conformation
Polyurethane
Polyurethane resins
Recyclability
Self healing materials
Sensors
Strain
Tensile strength
title Multi-functional self-healing polyurethane elastomer based on chair conformation for strain sensors
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