Hydrogen atom abstraction as a synthetic route to a square planar Co II complex with a redox-active tetradentate PNNP ligand

Redox-active ligands improve the reactivity of transition metal complexes by facilitating redox processes independent of the transition metal center. A tetradentate square planar (PNCH CH NP)Co (1) complex was synthesized and the ethylene backbone was dehydrogenated through hydrogen atom abstraction...

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Veröffentlicht in:Chemical science (Cambridge) 2024-09, Vol.15 (37), p.15311-15320
Hauptverfasser: Miller, Justin D, Walsh, Mitchell M, Lee, Kyounghoon, Moore, Curtis E, Thomas, Christine M
Format: Artikel
Sprache:eng
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