Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure
A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such...
Gespeichert in:
Veröffentlicht in: | RSC advances 2024-11, Vol.14 (49), p.36733-36744 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 36744 |
---|---|
container_issue | 49 |
container_start_page | 36733 |
container_title | RSC advances |
container_volume | 14 |
creator | Xu, Jiaxin Zheng, Yongjie Tian, Jingzhi Zhao, Yunpeng Zheng, Heshan |
description | A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO
Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such as Cu, ZnO, and TiO
, the removal efficiency of DBT reached 88.12% within a duration of 240 min. In the 5 repeated experiments, 7.5%Cu-ZnO/TiO
still exhibited high stability and could be reused. The improved photocatalytic performance of the 7.5%Cu-ZnO/TiO
composite can be attributed to its high light absorption capability and well-matched energy levels, which are due to the abundant presence of imperfections. The adoption of a Z-heterojunction has enabled efficient separation and transfer of photo-generated electrons and holes (e
/h
), thereby reducing the probability of charge carrier recombination. |
doi_str_mv | 10.1039/D4RA06833E |
format | Article |
fullrecord | <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D4RA06833E</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>39559580</sourcerecordid><originalsourceid>FETCH-LOGICAL-c580-3acd39cdeb9f0efd7f4b0055b47b2d28b5831b9f4ed52e5d211ce177920763fd3</originalsourceid><addsrcrecordid>eNpNkEtrwzAQhEVpaUKaS39A0bngRg_Lto7BddpCwBB86sVY0oq4-IVsHdJfX4f0tYfdgRl24EPonpInSrjcPIeHLYkSzrMrtGQkjAJGInn9Ty_Qehw_yDyRoCyit2jBpRBSJGSJDll3rDoNBhsYfWO9qz-rqe47PICzvWvPJu4tbnsDDbZ-XuqEUx-8d_mmqHPM8BEmcP04Oa8n7-AO3diqGWH9fVeo2GVF-hrs85e3dLsP9Nwc8EobLrUBJS0Ba2IbKkKEUGGsmGGJEgmnsxeCEQyEYZRqoHEsGYkjbg1focfLWz13jw5sObi6rdyppKQ8oyn_0Mzhh0t48KoF8xv9AcG_AJE1Xp4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure</title><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central Open Access</source><source>PubMed Central</source><creator>Xu, Jiaxin ; Zheng, Yongjie ; Tian, Jingzhi ; Zhao, Yunpeng ; Zheng, Heshan</creator><creatorcontrib>Xu, Jiaxin ; Zheng, Yongjie ; Tian, Jingzhi ; Zhao, Yunpeng ; Zheng, Heshan</creatorcontrib><description>A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO
Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such as Cu, ZnO, and TiO
, the removal efficiency of DBT reached 88.12% within a duration of 240 min. In the 5 repeated experiments, 7.5%Cu-ZnO/TiO
still exhibited high stability and could be reused. The improved photocatalytic performance of the 7.5%Cu-ZnO/TiO
composite can be attributed to its high light absorption capability and well-matched energy levels, which are due to the abundant presence of imperfections. The adoption of a Z-heterojunction has enabled efficient separation and transfer of photo-generated electrons and holes (e
/h
), thereby reducing the probability of charge carrier recombination.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/D4RA06833E</identifier><identifier>PMID: 39559580</identifier><language>eng</language><publisher>England</publisher><ispartof>RSC advances, 2024-11, Vol.14 (49), p.36733-36744</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c580-3acd39cdeb9f0efd7f4b0055b47b2d28b5831b9f4ed52e5d211ce177920763fd3</cites><orcidid>0000-0001-8506-0085</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39559580$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Jiaxin</creatorcontrib><creatorcontrib>Zheng, Yongjie</creatorcontrib><creatorcontrib>Tian, Jingzhi</creatorcontrib><creatorcontrib>Zhao, Yunpeng</creatorcontrib><creatorcontrib>Zheng, Heshan</creatorcontrib><title>Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO
Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such as Cu, ZnO, and TiO
, the removal efficiency of DBT reached 88.12% within a duration of 240 min. In the 5 repeated experiments, 7.5%Cu-ZnO/TiO
still exhibited high stability and could be reused. The improved photocatalytic performance of the 7.5%Cu-ZnO/TiO
composite can be attributed to its high light absorption capability and well-matched energy levels, which are due to the abundant presence of imperfections. The adoption of a Z-heterojunction has enabled efficient separation and transfer of photo-generated electrons and holes (e
/h
), thereby reducing the probability of charge carrier recombination.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpNkEtrwzAQhEVpaUKaS39A0bngRg_Lto7BddpCwBB86sVY0oq4-IVsHdJfX4f0tYfdgRl24EPonpInSrjcPIeHLYkSzrMrtGQkjAJGInn9Ty_Qehw_yDyRoCyit2jBpRBSJGSJDll3rDoNBhsYfWO9qz-rqe47PICzvWvPJu4tbnsDDbZ-XuqEUx-8d_mmqHPM8BEmcP04Oa8n7-AO3diqGWH9fVeo2GVF-hrs85e3dLsP9Nwc8EobLrUBJS0Ba2IbKkKEUGGsmGGJEgmnsxeCEQyEYZRqoHEsGYkjbg1focfLWz13jw5sObi6rdyppKQ8oyn_0Mzhh0t48KoF8xv9AcG_AJE1Xp4</recordid><startdate>20241111</startdate><enddate>20241111</enddate><creator>Xu, Jiaxin</creator><creator>Zheng, Yongjie</creator><creator>Tian, Jingzhi</creator><creator>Zhao, Yunpeng</creator><creator>Zheng, Heshan</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-8506-0085</orcidid></search><sort><creationdate>20241111</creationdate><title>Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure</title><author>Xu, Jiaxin ; Zheng, Yongjie ; Tian, Jingzhi ; Zhao, Yunpeng ; Zheng, Heshan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c580-3acd39cdeb9f0efd7f4b0055b47b2d28b5831b9f4ed52e5d211ce177920763fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Jiaxin</creatorcontrib><creatorcontrib>Zheng, Yongjie</creatorcontrib><creatorcontrib>Tian, Jingzhi</creatorcontrib><creatorcontrib>Zhao, Yunpeng</creatorcontrib><creatorcontrib>Zheng, Heshan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Jiaxin</au><au>Zheng, Yongjie</au><au>Tian, Jingzhi</au><au>Zhao, Yunpeng</au><au>Zheng, Heshan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2024-11-11</date><risdate>2024</risdate><volume>14</volume><issue>49</issue><spage>36733</spage><epage>36744</epage><pages>36733-36744</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO
Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such as Cu, ZnO, and TiO
, the removal efficiency of DBT reached 88.12% within a duration of 240 min. In the 5 repeated experiments, 7.5%Cu-ZnO/TiO
still exhibited high stability and could be reused. The improved photocatalytic performance of the 7.5%Cu-ZnO/TiO
composite can be attributed to its high light absorption capability and well-matched energy levels, which are due to the abundant presence of imperfections. The adoption of a Z-heterojunction has enabled efficient separation and transfer of photo-generated electrons and holes (e
/h
), thereby reducing the probability of charge carrier recombination.</abstract><cop>England</cop><pmid>39559580</pmid><doi>10.1039/D4RA06833E</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-8506-0085</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 2046-2069 |
ispartof | RSC advances, 2024-11, Vol.14 (49), p.36733-36744 |
issn | 2046-2069 2046-2069 |
language | eng |
recordid | cdi_crossref_primary_10_1039_D4RA06833E |
source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
title | Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T17%3A37%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhanced%20desulfurization%20performance%20of%20model%20fuel%20by%20Cu-ZnO/TiO%202%20heterostructure&rft.jtitle=RSC%20advances&rft.au=Xu,%20Jiaxin&rft.date=2024-11-11&rft.volume=14&rft.issue=49&rft.spage=36733&rft.epage=36744&rft.pages=36733-36744&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/D4RA06833E&rft_dat=%3Cpubmed_cross%3E39559580%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/39559580&rfr_iscdi=true |