Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure

A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such...

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Veröffentlicht in:RSC advances 2024-11, Vol.14 (49), p.36733-36744
Hauptverfasser: Xu, Jiaxin, Zheng, Yongjie, Tian, Jingzhi, Zhao, Yunpeng, Zheng, Heshan
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container_issue 49
container_start_page 36733
container_title RSC advances
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creator Xu, Jiaxin
Zheng, Yongjie
Tian, Jingzhi
Zhao, Yunpeng
Zheng, Heshan
description A facile hydrothermal approach was employed to synthesize a novel Cu-ZnO/TiO Z-heterojunction with a high density of defects, which was then utilized for the oxidative desulfurization process, demonstrating excellent photodegradation performance. The results showed that by adjusting components such as Cu, ZnO, and TiO , the removal efficiency of DBT reached 88.12% within a duration of 240 min. In the 5 repeated experiments, 7.5%Cu-ZnO/TiO still exhibited high stability and could be reused. The improved photocatalytic performance of the 7.5%Cu-ZnO/TiO composite can be attributed to its high light absorption capability and well-matched energy levels, which are due to the abundant presence of imperfections. The adoption of a Z-heterojunction has enabled efficient separation and transfer of photo-generated electrons and holes (e /h ), thereby reducing the probability of charge carrier recombination.
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title Enhanced desulfurization performance of model fuel by Cu-ZnO/TiO 2 heterostructure
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