Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts

Gold nanoparticle-loaded titania (Au/TiO ) inverse opals are highly ordered three-dimensional photonic structures with enhanced photocatalytic properties. However, fine control over the placement of the Au nanoparticles in the inverse opal structures remains challenging with traditional preparative...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Nanoscale 2024-07, Vol.16 (29), p.13867-13873
Hauptverfasser: Bijl, Marianne, Lim, Kang Rui Garrick, Garg, Sadhya, Nicolas, Natalie J, Visser, Nienke L, Aizenberg, Michael, van der Hoeven, Jessi E S, Aizenberg, Joanna
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 13873
container_issue 29
container_start_page 13867
container_title Nanoscale
container_volume 16
creator Bijl, Marianne
Lim, Kang Rui Garrick
Garg, Sadhya
Nicolas, Natalie J
Visser, Nienke L
Aizenberg, Michael
van der Hoeven, Jessi E S
Aizenberg, Joanna
description Gold nanoparticle-loaded titania (Au/TiO ) inverse opals are highly ordered three-dimensional photonic structures with enhanced photocatalytic properties. However, fine control over the placement of the Au nanoparticles in the inverse opal structures remains challenging with traditional preparative methods. Here, we present a multi-component co-assembly strategy to prepare high-quality Au/TiO inverse opal films in which Au nanoparticles are either located on, or inside the TiO matrix, as verified using electron tomography. We report that Au nanoparticles embedded in the TiO support exhibit enhanced thermal and mechanical stability compared to non-embedded nanoparticles that are more prone to both leaching and sintering.
doi_str_mv 10.1039/d4nr01200c
format Article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D4NR01200C</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>38979601</sourcerecordid><originalsourceid>FETCH-LOGICAL-c581-7c051e1e74162856c15a91eee9debbdd839fb0a50a9fea988eac020882dc55623</originalsourceid><addsrcrecordid>eNo9kE9LwzAYh4Mobk4vfgDJWah7kzRpchz1P8OB7F7S9K1WsrQknbBv73Tq6fccHn6Hh5BLBjcMhJk3eYjAOIA7IlMOOWRCFPz4n1U-IWcpfQAoI5Q4JROhTWEUsCl5Lvswxt77LrzRYEM_2Dh2ziMdvHW4wTDSLtDFdr7uVpTv-RNjQrr3PB3e-7F3drR-l8Z0Tk5a6xNe_O6MrO_v1uVjtlw9PJWLZeakZlnhQDJkWORMcS2VY9IahoimwbpuGi1MW4OVYE2L1miN1gEHrXnjpFRczMj14dbFPqWIbTXEbmPjrmJQffeobvOX158e5V6-OsjDtt5g86_-BRBfAqRbrA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Bijl, Marianne ; Lim, Kang Rui Garrick ; Garg, Sadhya ; Nicolas, Natalie J ; Visser, Nienke L ; Aizenberg, Michael ; van der Hoeven, Jessi E S ; Aizenberg, Joanna</creator><creatorcontrib>Bijl, Marianne ; Lim, Kang Rui Garrick ; Garg, Sadhya ; Nicolas, Natalie J ; Visser, Nienke L ; Aizenberg, Michael ; van der Hoeven, Jessi E S ; Aizenberg, Joanna</creatorcontrib><description>Gold nanoparticle-loaded titania (Au/TiO ) inverse opals are highly ordered three-dimensional photonic structures with enhanced photocatalytic properties. However, fine control over the placement of the Au nanoparticles in the inverse opal structures remains challenging with traditional preparative methods. Here, we present a multi-component co-assembly strategy to prepare high-quality Au/TiO inverse opal films in which Au nanoparticles are either located on, or inside the TiO matrix, as verified using electron tomography. We report that Au nanoparticles embedded in the TiO support exhibit enhanced thermal and mechanical stability compared to non-embedded nanoparticles that are more prone to both leaching and sintering.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d4nr01200c</identifier><identifier>PMID: 38979601</identifier><language>eng</language><publisher>England</publisher><ispartof>Nanoscale, 2024-07, Vol.16 (29), p.13867-13873</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c581-7c051e1e74162856c15a91eee9debbdd839fb0a50a9fea988eac020882dc55623</cites><orcidid>0000-0002-2901-7012 ; 0000-0003-2489-2448 ; 0000-0003-2159-9844 ; 0000-0002-2343-8705 ; 0000-0001-9832-289X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38979601$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bijl, Marianne</creatorcontrib><creatorcontrib>Lim, Kang Rui Garrick</creatorcontrib><creatorcontrib>Garg, Sadhya</creatorcontrib><creatorcontrib>Nicolas, Natalie J</creatorcontrib><creatorcontrib>Visser, Nienke L</creatorcontrib><creatorcontrib>Aizenberg, Michael</creatorcontrib><creatorcontrib>van der Hoeven, Jessi E S</creatorcontrib><creatorcontrib>Aizenberg, Joanna</creatorcontrib><title>Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Gold nanoparticle-loaded titania (Au/TiO ) inverse opals are highly ordered three-dimensional photonic structures with enhanced photocatalytic properties. However, fine control over the placement of the Au nanoparticles in the inverse opal structures remains challenging with traditional preparative methods. Here, we present a multi-component co-assembly strategy to prepare high-quality Au/TiO inverse opal films in which Au nanoparticles are either located on, or inside the TiO matrix, as verified using electron tomography. We report that Au nanoparticles embedded in the TiO support exhibit enhanced thermal and mechanical stability compared to non-embedded nanoparticles that are more prone to both leaching and sintering.</description><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9kE9LwzAYh4Mobk4vfgDJWah7kzRpchz1P8OB7F7S9K1WsrQknbBv73Tq6fccHn6Hh5BLBjcMhJk3eYjAOIA7IlMOOWRCFPz4n1U-IWcpfQAoI5Q4JROhTWEUsCl5Lvswxt77LrzRYEM_2Dh2ziMdvHW4wTDSLtDFdr7uVpTv-RNjQrr3PB3e-7F3drR-l8Z0Tk5a6xNe_O6MrO_v1uVjtlw9PJWLZeakZlnhQDJkWORMcS2VY9IahoimwbpuGi1MW4OVYE2L1miN1gEHrXnjpFRczMj14dbFPqWIbTXEbmPjrmJQffeobvOX158e5V6-OsjDtt5g86_-BRBfAqRbrA</recordid><startdate>20240725</startdate><enddate>20240725</enddate><creator>Bijl, Marianne</creator><creator>Lim, Kang Rui Garrick</creator><creator>Garg, Sadhya</creator><creator>Nicolas, Natalie J</creator><creator>Visser, Nienke L</creator><creator>Aizenberg, Michael</creator><creator>van der Hoeven, Jessi E S</creator><creator>Aizenberg, Joanna</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2901-7012</orcidid><orcidid>https://orcid.org/0000-0003-2489-2448</orcidid><orcidid>https://orcid.org/0000-0003-2159-9844</orcidid><orcidid>https://orcid.org/0000-0002-2343-8705</orcidid><orcidid>https://orcid.org/0000-0001-9832-289X</orcidid></search><sort><creationdate>20240725</creationdate><title>Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts</title><author>Bijl, Marianne ; Lim, Kang Rui Garrick ; Garg, Sadhya ; Nicolas, Natalie J ; Visser, Nienke L ; Aizenberg, Michael ; van der Hoeven, Jessi E S ; Aizenberg, Joanna</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c581-7c051e1e74162856c15a91eee9debbdd839fb0a50a9fea988eac020882dc55623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bijl, Marianne</creatorcontrib><creatorcontrib>Lim, Kang Rui Garrick</creatorcontrib><creatorcontrib>Garg, Sadhya</creatorcontrib><creatorcontrib>Nicolas, Natalie J</creatorcontrib><creatorcontrib>Visser, Nienke L</creatorcontrib><creatorcontrib>Aizenberg, Michael</creatorcontrib><creatorcontrib>van der Hoeven, Jessi E S</creatorcontrib><creatorcontrib>Aizenberg, Joanna</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bijl, Marianne</au><au>Lim, Kang Rui Garrick</au><au>Garg, Sadhya</au><au>Nicolas, Natalie J</au><au>Visser, Nienke L</au><au>Aizenberg, Michael</au><au>van der Hoeven, Jessi E S</au><au>Aizenberg, Joanna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2024-07-25</date><risdate>2024</risdate><volume>16</volume><issue>29</issue><spage>13867</spage><epage>13873</epage><pages>13867-13873</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Gold nanoparticle-loaded titania (Au/TiO ) inverse opals are highly ordered three-dimensional photonic structures with enhanced photocatalytic properties. However, fine control over the placement of the Au nanoparticles in the inverse opal structures remains challenging with traditional preparative methods. Here, we present a multi-component co-assembly strategy to prepare high-quality Au/TiO inverse opal films in which Au nanoparticles are either located on, or inside the TiO matrix, as verified using electron tomography. We report that Au nanoparticles embedded in the TiO support exhibit enhanced thermal and mechanical stability compared to non-embedded nanoparticles that are more prone to both leaching and sintering.</abstract><cop>England</cop><pmid>38979601</pmid><doi>10.1039/d4nr01200c</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2901-7012</orcidid><orcidid>https://orcid.org/0000-0003-2489-2448</orcidid><orcidid>https://orcid.org/0000-0003-2159-9844</orcidid><orcidid>https://orcid.org/0000-0002-2343-8705</orcidid><orcidid>https://orcid.org/0000-0001-9832-289X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2040-3364
ispartof Nanoscale, 2024-07, Vol.16 (29), p.13867-13873
issn 2040-3364
2040-3372
language eng
recordid cdi_crossref_primary_10_1039_D4NR01200C
source Royal Society Of Chemistry Journals 2008-
title Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T18%3A07%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Controlling%20nanoparticle%20placement%20in%20Au/TiO%202%20inverse%20opal%20photocatalysts&rft.jtitle=Nanoscale&rft.au=Bijl,%20Marianne&rft.date=2024-07-25&rft.volume=16&rft.issue=29&rft.spage=13867&rft.epage=13873&rft.pages=13867-13873&rft.issn=2040-3364&rft.eissn=2040-3372&rft_id=info:doi/10.1039/d4nr01200c&rft_dat=%3Cpubmed_cross%3E38979601%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/38979601&rfr_iscdi=true