Interactions between alkali cations and cyanide-bridged network in A 2 Co 4 [Fe(CN) 6 ] 3.3 Prussian blue analogues revealed by far-infrared spectroscopy

A series of Prussian Blue Analogues (PBAs) having the chemical formula A 2 Co 4 [Fe(CN) 6 ] 3.3 · n H 2 O (A + = Na + , Rb + and Cs + ) was investigated by variable temperature far-infrared spectroscopy. Despite the same chemical composition of the cyanide-bridged CoFe network, the three compounds a...

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Veröffentlicht in:Materials advances 2024-05, Vol.5 (9), p.3794-3801
Hauptverfasser: Dronova, Maria, Altenschmidt, Laura, Bordage, Amélie, Brubach, Jean-Blaise, Verseils, Marine, Balthazar, Gregory, Roy, Pascale, Bleuzen, Anne
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Sprache:eng
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