A safer, greener and faster synthesis process of sodium azide by simply altering the alcohol reactant

Sodium azide production suffers from safety hazards and environmental pollution rooted in the reduction reaction between alkyl nitrites and hydrazine hydrate. To enhance this heterogenous reaction, nitrites synthesized from small molecule fatty alcohols are widely used to increase its solubility in...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2024-05, Vol.26 (1), p.6139-6149
Hauptverfasser:	Yan, Zifei, Deng, Jian, Tian, Jiaxin, Luo, Guangsheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Benzyl alcohol Boiling point Boiling points Chemical reduction Chemical synthesis Distillation Emissions Environmental pollution Esters Hydrates Hydrazine Hydrazines Intermediates Nitrites Reaction mechanisms Reaction time Safety Sodium Sodium azide Sodium azides Solubility VOCs Volatile organic compounds
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