Neutral mononuclear indium(III) photosensitizers for CO 2 photoreduction
Herein, neutral mononuclear indium(III) complexes (In-1-In-3) containing 2,6-di(1 -pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the cl...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-11, Vol.53 (44), p.17772-17776 |
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| container_issue | 44 |
| container_start_page | 17772 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 53 |
| creator | Zhang, Zaichao Fu, Li-Zhi He, Piao Yi, Xiao-Yi |
| description | Herein, neutral mononuclear indium(III) complexes (In-1-In-3) containing 2,6-di(1
-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO
reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)
. The amount of CO generation is 28.4 μmol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH
CN media. |
| doi_str_mv | 10.1039/d4dt02595d |
| format | Article |
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-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO
reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)
. The amount of CO generation is 28.4 μmol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH
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-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO
reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)
. The amount of CO generation is 28.4 μmol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH
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-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO
reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)
. The amount of CO generation is 28.4 μmol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH
CN media.</abstract><cop>England</cop><pmid>39474851</pmid><doi>10.1039/d4dt02595d</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5482-9496</orcidid><orcidid>https://orcid.org/0000-0003-2500-7578</orcidid></addata></record> |
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| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-11, Vol.53 (44), p.17772-17776 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_D4DT02595D |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Neutral mononuclear indium(III) photosensitizers for CO 2 photoreduction |
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