Facile synthesis of five-membered cyclic RE 2 P-H iron(0) complexes
The synthesis of five-membered P-heterocyclic iron(0) complexes possessing a P-H unit and two heteroatoms (E = O, N), directly bound to phosphorus, is described. Initial problems to achieve access "classical" reduction of P-Cl bonds of P-heterocycle complexes, , leading to P-P coupling, co...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-08, Vol.53 (31), p.13201-13206 |
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| container_end_page | 13206 |
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| container_issue | 31 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 53 |
| creator | Brehm, Philipp C Schnakenburg, Gregor Streubel, Rainer |
| description | The synthesis of five-membered P-heterocyclic iron(0) complexes possessing a P-H unit and two heteroatoms (E = O, N), directly bound to phosphorus, is described. Initial problems to achieve access
"classical" reduction of P-Cl bonds of P-heterocycle complexes,
, leading to P-P coupling, could be solved by a "combined two-step" reduction/complexation. The use of K[Fe(CO)
H] not only opened access to such heterocyclic phosphane Fe(CO)
complexes but also allowed the synthesis of sterically non-shielded 'secondary' heterocyclic phosphane complexes. Spectroscopic and structural parameters are discussed. |
| doi_str_mv | 10.1039/D4DT01313A |
| format | Article |
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"classical" reduction of P-Cl bonds of P-heterocycle complexes,
, leading to P-P coupling, could be solved by a "combined two-step" reduction/complexation. The use of K[Fe(CO)
H] not only opened access to such heterocyclic phosphane Fe(CO)
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"classical" reduction of P-Cl bonds of P-heterocycle complexes,
, leading to P-P coupling, could be solved by a "combined two-step" reduction/complexation. The use of K[Fe(CO)
H] not only opened access to such heterocyclic phosphane Fe(CO)
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"classical" reduction of P-Cl bonds of P-heterocycle complexes,
, leading to P-P coupling, could be solved by a "combined two-step" reduction/complexation. The use of K[Fe(CO)
H] not only opened access to such heterocyclic phosphane Fe(CO)
complexes but also allowed the synthesis of sterically non-shielded 'secondary' heterocyclic phosphane complexes. Spectroscopic and structural parameters are discussed.</abstract><cop>England</cop><pmid>39049615</pmid><doi>10.1039/D4DT01313A</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-6489-2106</orcidid><orcidid>https://orcid.org/0000-0002-6507-003X</orcidid><orcidid>https://orcid.org/0000-0001-5661-8502</orcidid></addata></record> |
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| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-08, Vol.53 (31), p.13201-13206 |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Facile synthesis of five-membered cyclic RE 2 P-H iron(0) complexes |
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