Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer
We used phytate coordination on a Cu surface to overcome the kinetic bottleneck for proton adsorption/activation through a concerted proton-coupled electron transfer pathway; this leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis. Phytate coordination effec...
Gespeichert in:
| Veröffentlicht in: | Catalysis science & technology 2024-08, Vol.14 (16), p.4466-447 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 447 |
|---|---|
| container_issue | 16 |
| container_start_page | 4466 |
| container_title | Catalysis science & technology |
| container_volume | 14 |
| creator | Yu, Guanqiao Guo, Zilu Li, Yuefei Huang, Shan Li, Jiayuan |
| description | We used phytate coordination on a Cu surface to overcome the kinetic bottleneck for proton adsorption/activation through a concerted proton-coupled electron transfer pathway; this leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.
Phytate coordination effectively accelerates proton adsorption/activation kinetics through a concerted proton-coupled electron transfer pathway. This leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis. |
| doi_str_mv | 10.1039/d4cy00799a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D4CY00799A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3091648291</sourcerecordid><originalsourceid>FETCH-LOGICAL-c170t-ff2b3b3374638a7a015aad588bdd0635cf670f687bc68d59ba2ed86234899c2b3</originalsourceid><addsrcrecordid>eNpFkM1LAzEQxYMoWGov3oUFb8Jqssnm41iq1ULBix48hWw2sVt2k5pkhf73RlvqXGYGfu_N8AC4RvAeQSweWqL3EDIh1BmYVJCQkjCKzk9zjS_BLMYtzEUEgryaALkadsF_m7ZwXQoqmTL5Ug2Dd50qTG90Cl6rpPp97GKRNsGPn5tCe6dNSFmVxcm7Uvtx1-f1qHBF9nLRmnAFLqzqo5kd-xS8L5_eFi_l-vV5tZivS40YTKW1VYMbjBmhmCumIKqVamvOm7aFFNfaUgYt5azRlLe1aFRlWk4rTLgQOmun4Pbgmx_6Gk1McuvH4PJJiaFAlPBKoEzdHSgdfIzBWLkL3aDCXiIofzOUj2Tx8ZfhPMM3BzhEfeL-M8Y_3Vlv0Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3091648291</pqid></control><display><type>article</type><title>Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Yu, Guanqiao ; Guo, Zilu ; Li, Yuefei ; Huang, Shan ; Li, Jiayuan</creator><creatorcontrib>Yu, Guanqiao ; Guo, Zilu ; Li, Yuefei ; Huang, Shan ; Li, Jiayuan</creatorcontrib><description>We used phytate coordination on a Cu surface to overcome the kinetic bottleneck for proton adsorption/activation through a concerted proton-coupled electron transfer pathway; this leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.
Phytate coordination effectively accelerates proton adsorption/activation kinetics through a concerted proton-coupled electron transfer pathway. This leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.</description><identifier>ISSN: 2044-4753</identifier><identifier>EISSN: 2044-4761</identifier><identifier>DOI: 10.1039/d4cy00799a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Ammonia ; Electrocatalysis ; Electron transfer ; Protons</subject><ispartof>Catalysis science & technology, 2024-08, Vol.14 (16), p.4466-447</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-ff2b3b3374638a7a015aad588bdd0635cf670f687bc68d59ba2ed86234899c2b3</cites><orcidid>0000-0002-0781-3958</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Yu, Guanqiao</creatorcontrib><creatorcontrib>Guo, Zilu</creatorcontrib><creatorcontrib>Li, Yuefei</creatorcontrib><creatorcontrib>Huang, Shan</creatorcontrib><creatorcontrib>Li, Jiayuan</creatorcontrib><title>Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer</title><title>Catalysis science & technology</title><description>We used phytate coordination on a Cu surface to overcome the kinetic bottleneck for proton adsorption/activation through a concerted proton-coupled electron transfer pathway; this leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.
Phytate coordination effectively accelerates proton adsorption/activation kinetics through a concerted proton-coupled electron transfer pathway. This leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.</description><subject>Ammonia</subject><subject>Electrocatalysis</subject><subject>Electron transfer</subject><subject>Protons</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkM1LAzEQxYMoWGov3oUFb8Jqssnm41iq1ULBix48hWw2sVt2k5pkhf73RlvqXGYGfu_N8AC4RvAeQSweWqL3EDIh1BmYVJCQkjCKzk9zjS_BLMYtzEUEgryaALkadsF_m7ZwXQoqmTL5Ug2Dd50qTG90Cl6rpPp97GKRNsGPn5tCe6dNSFmVxcm7Uvtx1-f1qHBF9nLRmnAFLqzqo5kd-xS8L5_eFi_l-vV5tZivS40YTKW1VYMbjBmhmCumIKqVamvOm7aFFNfaUgYt5azRlLe1aFRlWk4rTLgQOmun4Pbgmx_6Gk1McuvH4PJJiaFAlPBKoEzdHSgdfIzBWLkL3aDCXiIofzOUj2Tx8ZfhPMM3BzhEfeL-M8Y_3Vlv0Q</recordid><startdate>20240812</startdate><enddate>20240812</enddate><creator>Yu, Guanqiao</creator><creator>Guo, Zilu</creator><creator>Li, Yuefei</creator><creator>Huang, Shan</creator><creator>Li, Jiayuan</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-0781-3958</orcidid></search><sort><creationdate>20240812</creationdate><title>Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer</title><author>Yu, Guanqiao ; Guo, Zilu ; Li, Yuefei ; Huang, Shan ; Li, Jiayuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-ff2b3b3374638a7a015aad588bdd0635cf670f687bc68d59ba2ed86234899c2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ammonia</topic><topic>Electrocatalysis</topic><topic>Electron transfer</topic><topic>Protons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Guanqiao</creatorcontrib><creatorcontrib>Guo, Zilu</creatorcontrib><creatorcontrib>Li, Yuefei</creatorcontrib><creatorcontrib>Huang, Shan</creatorcontrib><creatorcontrib>Li, Jiayuan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Guanqiao</au><au>Guo, Zilu</au><au>Li, Yuefei</au><au>Huang, Shan</au><au>Li, Jiayuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer</atitle><jtitle>Catalysis science & technology</jtitle><date>2024-08-12</date><risdate>2024</risdate><volume>14</volume><issue>16</issue><spage>4466</spage><epage>447</epage><pages>4466-447</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>We used phytate coordination on a Cu surface to overcome the kinetic bottleneck for proton adsorption/activation through a concerted proton-coupled electron transfer pathway; this leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.
Phytate coordination effectively accelerates proton adsorption/activation kinetics through a concerted proton-coupled electron transfer pathway. This leads to one order of magnitude activity enhancement for nitrate-to-ammonia electrocatalysis.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4cy00799a</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-0781-3958</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2044-4753 |
| ispartof | Catalysis science & technology, 2024-08, Vol.14 (16), p.4466-447 |
| issn | 2044-4753 2044-4761 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D4CY00799A |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Ammonia Electrocatalysis Electron transfer Protons |
| title | Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T01%3A55%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Improved%20nitrate-to-ammonia%20electrocatalysis%20through%20concerted%20proton-coupled%20electron%20transfer&rft.jtitle=Catalysis%20science%20&%20technology&rft.au=Yu,%20Guanqiao&rft.date=2024-08-12&rft.volume=14&rft.issue=16&rft.spage=4466&rft.epage=447&rft.pages=4466-447&rft.issn=2044-4753&rft.eissn=2044-4761&rft_id=info:doi/10.1039/d4cy00799a&rft_dat=%3Cproquest_cross%3E3091648291%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3091648291&rft_id=info:pmid/&rfr_iscdi=true |