Regiodivergent C-H alkynylation of 2-arylthiazoles switched by Ru II and Pd II catalysis

Two complementary regiodivergent C-H alkynylations of 2-arylthiazoles are reported. When Ru catalysis is employed, an aryl -alkynylation process is favored. The alkynylated products are gained in good yields. With the use of Pd catalysis, a thiazole C5-alkynylation process is developed, allowing for...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-06, Vol.60 (52), p.6679-6682
Hauptverfasser: Zhou, Pengfei, Liang, Xinyao, Xu, Zekun, Chen, Honggu, Wei, Zongwu, Liang, Taoyuan, Jiang, Jun, Zhang, Zhuan
Format: Artikel
Sprache:eng
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