Copper salt of a DABCO-based molten salt: a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives
In this study, [DABCO](SO 3 H) 2 CuCl 4 as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. The identif...
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| Veröffentlicht in: | RSC advances 2023-11, Vol.13 (5), p.35659-35671 |
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| creator | Fekrat, Neamatullah Mazloumi, Masoumeh Shirini, Farhad |
| description | In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. The identification of this catalyst was accomplished by using techniques such as infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo gravimetric analysis (TGA), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDS) spectroscopy. Excellent efficiency, short reaction times, a simple working method and also use of a recyclable catalyst are the considerable advantages of this process.
In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. |
| doi_str_mv | 10.1039/d3ra07366a |
| format | Article |
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3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. The identification of this catalyst was accomplished by using techniques such as infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo gravimetric analysis (TGA), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDS) spectroscopy. Excellent efficiency, short reaction times, a simple working method and also use of a recyclable catalyst are the considerable advantages of this process.
In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra07366a</identifier><identifier>PMID: 38077967</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Catalysts ; Chemical synthesis ; Emission analysis ; Field emission microscopy ; Infrared analysis ; Infrared spectroscopy ; Molten salts ; Thermogravimetric analysis</subject><ispartof>RSC advances, 2023-11, Vol.13 (5), p.35659-35671</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c332t-6e7964ca9d78f8c87766a02b567a0114a6a64a94b8e37d8c19c8e33970d346763</cites><orcidid>0000-0002-7204-5000</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38077967$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fekrat, Neamatullah</creatorcontrib><creatorcontrib>Mazloumi, Masoumeh</creatorcontrib><creatorcontrib>Shirini, Farhad</creatorcontrib><title>Copper salt of a DABCO-based molten salt: a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. The identification of this catalyst was accomplished by using techniques such as infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo gravimetric analysis (TGA), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDS) spectroscopy. Excellent efficiency, short reaction times, a simple working method and also use of a recyclable catalyst are the considerable advantages of this process.
In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives.</description><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Emission analysis</subject><subject>Field emission microscopy</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Molten salts</subject><subject>Thermogravimetric analysis</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkU1v1DAQhi0EolXphTvIEheESHE8qR1z2275qFSpEoJzNGs7rKvEDra3Uv5Kfy3ObikIXzwfj17NzEvIy5qd1QzUBwMRmQQh8Ak55qwRFWdCPf0nPiKnKd2y8sR5zUX9nBxBy6RUQh6T-3WYJhtpwiHT0FOkl6uL9U21wWQNHcOQrd83P5bW1v3cVoXuQxzRa0s1ZhzmlKnzNG8tDd5WU8g0zb6kyaVFEt43lXHb2cQwzdGNzjhvKXpDpzDM-_qvnfNhWMrGRneH2d3Z9II863FI9vThPyE_Pn_6vv5aXd98uVqvrisNwHMlbNmk0aiMbPtWt1KWWzC-ORcSWV03KFA0qJpNa0GaVtdKlwiUZAYaIQWckLcH3WkZxKbcjS5pOwzobdiljivGFbTAeUHf_Ifehl30ZbqFAq7K0aFQ7w6UjiGlaPtuKmtjnLuadYtp3SV8W-1NWxX49YPkbjNa84j-sagArw5ATPqx-9d1-A0t85wG</recordid><startdate>20231130</startdate><enddate>20231130</enddate><creator>Fekrat, Neamatullah</creator><creator>Mazloumi, Masoumeh</creator><creator>Shirini, Farhad</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7204-5000</orcidid></search><sort><creationdate>20231130</creationdate><title>Copper salt of a DABCO-based molten salt: a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives</title><author>Fekrat, Neamatullah ; Mazloumi, Masoumeh ; Shirini, Farhad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-6e7964ca9d78f8c87766a02b567a0114a6a64a94b8e37d8c19c8e33970d346763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Emission analysis</topic><topic>Field emission microscopy</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Molten salts</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fekrat, Neamatullah</creatorcontrib><creatorcontrib>Mazloumi, Masoumeh</creatorcontrib><creatorcontrib>Shirini, Farhad</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fekrat, Neamatullah</au><au>Mazloumi, Masoumeh</au><au>Shirini, Farhad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper salt of a DABCO-based molten salt: a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-11-30</date><risdate>2023</risdate><volume>13</volume><issue>5</issue><spage>35659</spage><epage>35671</epage><pages>35659-35671</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives. The identification of this catalyst was accomplished by using techniques such as infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo gravimetric analysis (TGA), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDS) spectroscopy. Excellent efficiency, short reaction times, a simple working method and also use of a recyclable catalyst are the considerable advantages of this process.
In this study, [DABCO](SO
3
H)
2
CuCl
4
as a novel DABCO-based molten salt with dual acidic functionality (Brønsted and Lewis) has been synthesized, characterized and used as a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38077967</pmid><doi>10.1039/d3ra07366a</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-7204-5000</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | RSC advances, 2023-11, Vol.13 (5), p.35659-35671 |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Catalysts Chemical synthesis Emission analysis Field emission microscopy Infrared analysis Infrared spectroscopy Molten salts Thermogravimetric analysis |
| title | Copper salt of a DABCO-based molten salt: a high-performance catalyst in the one-pot synthesis of 3,4-dihydropyrimidine and polyhydroquinoline derivatives |
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