Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties

Near-infrared (NIR) radiation has generated considerable industrial and research interest. However, NIR phosphors for this are limited by low quantum efficiency and broad spectra. Rare-earth-containing compounds doped with activators as host systems for NIR phosphors may resolve these limitations. Y...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2023-03, Vol.13 (11), p.7597-7602
Hauptverfasser: Kang, Tae Wook, Choi, Yeon Bin, Kang, Chae Ha, Park, Young Ji, Kim, Jin Ho, Bae, Byungseo, Kim, Sun Woog
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7602
container_issue 11
container_start_page 7597
container_title RSC advances
container_volume 13
creator Kang, Tae Wook
Choi, Yeon Bin
Kang, Chae Ha
Park, Young Ji
Kim, Jin Ho
Bae, Byungseo
Kim, Sun Woog
description Near-infrared (NIR) radiation has generated considerable industrial and research interest. However, NIR phosphors for this are limited by low quantum efficiency and broad spectra. Rare-earth-containing compounds doped with activators as host systems for NIR phosphors may resolve these limitations. Yb -doped NaY Si O phosphors were synthesized using a conventional solid-state reaction method. The main phase of the synthesized phosphor samples exhibited a hexagonal structure NaY Si O phase, and had an angular-shape with an average grain size of 1-3 μm. The NaY Si O :Yb phosphors showed a near-infrared emission from 950 to 1100 nm, which was attributed to the F → F transition of Yb ions under 270 and 920 nm excitation. The excitation spectra, recorded by monitoring the emission at 985 nm, showed two bands in the ultraviolet and infrared regions, which correspond to the charge transfer transition and the F → F transition of Yb ions. At 300 °C, the emission intensity of the NaY Si O :Yb phosphor remained constant at 82%. Furthermore, the thermal degradation was negligible after cooling, suggesting the possibility of application in advanced anti-counterfeiting applications.
doi_str_mv 10.1039/d3ra00427a
format Article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D3RA00427A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>36908548</sourcerecordid><originalsourceid>FETCH-LOGICAL-c998-4fec9a476063b8e30f8a1c5a4ea9b84d1cd88dbbec3f74c62531fe9b783c763</originalsourceid><addsrcrecordid>eNpNkN1KAzEQhYMoKrU3PoDMtbKa3WyziXfF-gfSQvXGq5LNTrqR_SPJKn0dn9StVXFgmLn4zpzhEHIa08uYMnlVMKcoTZNM7ZHjhKY8SiiX-__2IzL2_o0OxSdxwuNDcsS4pGKSimPyOcN3rNquxiZAa2CuXkHCswUOC0g4XL_mwC6gK1s_tPPwYUMJpV2XEEp0tarAB5XbyoYNmNbB_HEJqgk20m3fBHQGbbDN-nrA-mKztbDBg3abQbbVul6H3uGgKaDqa9ug19tfOtd26IJFf0IOjKo8jn_miCzvbl9uHqKnxf3jzfQp0lKKKDWopUozTjnLBTJqhIr1RKWoZC7SItaFEEWeo2YmSzVPJiw2KPNMMJ1xNiLnu6Patd47NKvO2Vq5zSqmq23QqxlbTr-Dng7w2Q7u-rzG4g_9jZV9AUKxeuQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Kang, Tae Wook ; Choi, Yeon Bin ; Kang, Chae Ha ; Park, Young Ji ; Kim, Jin Ho ; Bae, Byungseo ; Kim, Sun Woog</creator><creatorcontrib>Kang, Tae Wook ; Choi, Yeon Bin ; Kang, Chae Ha ; Park, Young Ji ; Kim, Jin Ho ; Bae, Byungseo ; Kim, Sun Woog</creatorcontrib><description>Near-infrared (NIR) radiation has generated considerable industrial and research interest. However, NIR phosphors for this are limited by low quantum efficiency and broad spectra. Rare-earth-containing compounds doped with activators as host systems for NIR phosphors may resolve these limitations. Yb -doped NaY Si O phosphors were synthesized using a conventional solid-state reaction method. The main phase of the synthesized phosphor samples exhibited a hexagonal structure NaY Si O phase, and had an angular-shape with an average grain size of 1-3 μm. The NaY Si O :Yb phosphors showed a near-infrared emission from 950 to 1100 nm, which was attributed to the F → F transition of Yb ions under 270 and 920 nm excitation. The excitation spectra, recorded by monitoring the emission at 985 nm, showed two bands in the ultraviolet and infrared regions, which correspond to the charge transfer transition and the F → F transition of Yb ions. At 300 °C, the emission intensity of the NaY Si O :Yb phosphor remained constant at 82%. Furthermore, the thermal degradation was negligible after cooling, suggesting the possibility of application in advanced anti-counterfeiting applications.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra00427a</identifier><identifier>PMID: 36908548</identifier><language>eng</language><publisher>England</publisher><ispartof>RSC advances, 2023-03, Vol.13 (11), p.7597-7602</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c998-4fec9a476063b8e30f8a1c5a4ea9b84d1cd88dbbec3f74c62531fe9b783c763</citedby><cites>FETCH-LOGICAL-c998-4fec9a476063b8e30f8a1c5a4ea9b84d1cd88dbbec3f74c62531fe9b783c763</cites><orcidid>0000-0001-5250-5041 ; 0000-0001-8867-4031 ; 0000-0002-0317-2612</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36908548$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kang, Tae Wook</creatorcontrib><creatorcontrib>Choi, Yeon Bin</creatorcontrib><creatorcontrib>Kang, Chae Ha</creatorcontrib><creatorcontrib>Park, Young Ji</creatorcontrib><creatorcontrib>Kim, Jin Ho</creatorcontrib><creatorcontrib>Bae, Byungseo</creatorcontrib><creatorcontrib>Kim, Sun Woog</creatorcontrib><title>Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Near-infrared (NIR) radiation has generated considerable industrial and research interest. However, NIR phosphors for this are limited by low quantum efficiency and broad spectra. Rare-earth-containing compounds doped with activators as host systems for NIR phosphors may resolve these limitations. Yb -doped NaY Si O phosphors were synthesized using a conventional solid-state reaction method. The main phase of the synthesized phosphor samples exhibited a hexagonal structure NaY Si O phase, and had an angular-shape with an average grain size of 1-3 μm. The NaY Si O :Yb phosphors showed a near-infrared emission from 950 to 1100 nm, which was attributed to the F → F transition of Yb ions under 270 and 920 nm excitation. The excitation spectra, recorded by monitoring the emission at 985 nm, showed two bands in the ultraviolet and infrared regions, which correspond to the charge transfer transition and the F → F transition of Yb ions. At 300 °C, the emission intensity of the NaY Si O :Yb phosphor remained constant at 82%. Furthermore, the thermal degradation was negligible after cooling, suggesting the possibility of application in advanced anti-counterfeiting applications.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkN1KAzEQhYMoKrU3PoDMtbKa3WyziXfF-gfSQvXGq5LNTrqR_SPJKn0dn9StVXFgmLn4zpzhEHIa08uYMnlVMKcoTZNM7ZHjhKY8SiiX-__2IzL2_o0OxSdxwuNDcsS4pGKSimPyOcN3rNquxiZAa2CuXkHCswUOC0g4XL_mwC6gK1s_tPPwYUMJpV2XEEp0tarAB5XbyoYNmNbB_HEJqgk20m3fBHQGbbDN-nrA-mKztbDBg3abQbbVul6H3uGgKaDqa9ug19tfOtd26IJFf0IOjKo8jn_miCzvbl9uHqKnxf3jzfQp0lKKKDWopUozTjnLBTJqhIr1RKWoZC7SItaFEEWeo2YmSzVPJiw2KPNMMJ1xNiLnu6Patd47NKvO2Vq5zSqmq23QqxlbTr-Dng7w2Q7u-rzG4g_9jZV9AUKxeuQ</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Kang, Tae Wook</creator><creator>Choi, Yeon Bin</creator><creator>Kang, Chae Ha</creator><creator>Park, Young Ji</creator><creator>Kim, Jin Ho</creator><creator>Bae, Byungseo</creator><creator>Kim, Sun Woog</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5250-5041</orcidid><orcidid>https://orcid.org/0000-0001-8867-4031</orcidid><orcidid>https://orcid.org/0000-0002-0317-2612</orcidid></search><sort><creationdate>20230301</creationdate><title>Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties</title><author>Kang, Tae Wook ; Choi, Yeon Bin ; Kang, Chae Ha ; Park, Young Ji ; Kim, Jin Ho ; Bae, Byungseo ; Kim, Sun Woog</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c998-4fec9a476063b8e30f8a1c5a4ea9b84d1cd88dbbec3f74c62531fe9b783c763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kang, Tae Wook</creatorcontrib><creatorcontrib>Choi, Yeon Bin</creatorcontrib><creatorcontrib>Kang, Chae Ha</creatorcontrib><creatorcontrib>Park, Young Ji</creatorcontrib><creatorcontrib>Kim, Jin Ho</creatorcontrib><creatorcontrib>Bae, Byungseo</creatorcontrib><creatorcontrib>Kim, Sun Woog</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kang, Tae Wook</au><au>Choi, Yeon Bin</au><au>Kang, Chae Ha</au><au>Park, Young Ji</au><au>Kim, Jin Ho</au><au>Bae, Byungseo</au><au>Kim, Sun Woog</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-03-01</date><risdate>2023</risdate><volume>13</volume><issue>11</issue><spage>7597</spage><epage>7602</epage><pages>7597-7602</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Near-infrared (NIR) radiation has generated considerable industrial and research interest. However, NIR phosphors for this are limited by low quantum efficiency and broad spectra. Rare-earth-containing compounds doped with activators as host systems for NIR phosphors may resolve these limitations. Yb -doped NaY Si O phosphors were synthesized using a conventional solid-state reaction method. The main phase of the synthesized phosphor samples exhibited a hexagonal structure NaY Si O phase, and had an angular-shape with an average grain size of 1-3 μm. The NaY Si O :Yb phosphors showed a near-infrared emission from 950 to 1100 nm, which was attributed to the F → F transition of Yb ions under 270 and 920 nm excitation. The excitation spectra, recorded by monitoring the emission at 985 nm, showed two bands in the ultraviolet and infrared regions, which correspond to the charge transfer transition and the F → F transition of Yb ions. At 300 °C, the emission intensity of the NaY Si O :Yb phosphor remained constant at 82%. Furthermore, the thermal degradation was negligible after cooling, suggesting the possibility of application in advanced anti-counterfeiting applications.</abstract><cop>England</cop><pmid>36908548</pmid><doi>10.1039/d3ra00427a</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-5250-5041</orcidid><orcidid>https://orcid.org/0000-0001-8867-4031</orcidid><orcidid>https://orcid.org/0000-0002-0317-2612</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2046-2069
ispartof RSC advances, 2023-03, Vol.13 (11), p.7597-7602
issn 2046-2069
2046-2069
language eng
recordid cdi_crossref_primary_10_1039_D3RA00427A
source DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central
title Development of NaY 9 Si 6 O 26 :Yb 3+ phosphors with high thermal stability for NIR anti-counterfeiting: study of its crystal structure and luminescent properties
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T00%3A38%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Development%20of%20NaY%209%20Si%206%20O%2026%20:Yb%203+%20phosphors%20with%20high%20thermal%20stability%20for%20NIR%20anti-counterfeiting:%20study%20of%20its%20crystal%20structure%20and%20luminescent%20properties&rft.jtitle=RSC%20advances&rft.au=Kang,%20Tae%20Wook&rft.date=2023-03-01&rft.volume=13&rft.issue=11&rft.spage=7597&rft.epage=7602&rft.pages=7597-7602&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/d3ra00427a&rft_dat=%3Cpubmed_cross%3E36908548%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/36908548&rfr_iscdi=true