Recent progress in organic-metal complexes for organic photovoltaic applications
Organic-metal complexes (OMCs) combine the functions of metals with mechanical properties and organic molecules with solution-processing properties, endowing them with the valence change characteristics of metal ions and diversity of organic molecular structures. Moreover, the coordination mode betw...
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| Veröffentlicht in: | Materials chemistry frontiers 2023-10, Vol.7 (21), p.563-513 |
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| creator | Lv, Qianglong Yu, Runnan Shi, Rui Tan, Zhan'ao |
| description | Organic-metal complexes (OMCs) combine the functions of metals with mechanical properties and organic molecules with solution-processing properties, endowing them with the valence change characteristics of metal ions and diversity of organic molecular structures. Moreover, the coordination mode between the metal cations and organic ligands is flexible, enabling the application of OMCs in a wide variety of low-cost electronic and optoelectronic devices. As an important field of optoelectronic research, the applications of OMCs such as phthalocyanine-, porphyrin-, platinum- and ruthenium-based metal complexes in organic photovoltaic solar cells (OSCs) as the active layer, transport layer and additives are reviewed. The performance enhancements in OSCs are closely related to the structures and properties of OMCs. Herein, we provide an in-depth analysis of the structure-performance relationships of OMCs. Finally, perspectives on the opportunities and challenges of these materials are given. It is hoped that this review will inspire the development of OMCs for advanced OSCs.
Organic-metal complexes (OMCs) are endowed with new functions and properties due to the characteristics of valence changes of metal ions and the diversity of organic molecular structures. |
| doi_str_mv | 10.1039/d3qm00603d |
| format | Article |
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Organic-metal complexes (OMCs) are endowed with new functions and properties due to the characteristics of valence changes of metal ions and the diversity of organic molecular structures.</description><identifier>ISSN: 2052-1537</identifier><identifier>EISSN: 2052-1537</identifier><identifier>DOI: 10.1039/d3qm00603d</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Additives ; Coordination compounds ; Mechanical properties ; Molecular structure ; Optoelectronic devices ; Organic chemistry ; Photovoltaic cells ; Porphyrins ; Ruthenium ; Solar cells</subject><ispartof>Materials chemistry frontiers, 2023-10, Vol.7 (21), p.563-513</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-13753c1ead463419a41ec797bb8d33347e6d81653f30db1483b9765a17f6ff103</citedby><cites>FETCH-LOGICAL-c281t-13753c1ead463419a41ec797bb8d33347e6d81653f30db1483b9765a17f6ff103</cites><orcidid>0000-0003-2700-4725</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lv, Qianglong</creatorcontrib><creatorcontrib>Yu, Runnan</creatorcontrib><creatorcontrib>Shi, Rui</creatorcontrib><creatorcontrib>Tan, Zhan'ao</creatorcontrib><title>Recent progress in organic-metal complexes for organic photovoltaic applications</title><title>Materials chemistry frontiers</title><description>Organic-metal complexes (OMCs) combine the functions of metals with mechanical properties and organic molecules with solution-processing properties, endowing them with the valence change characteristics of metal ions and diversity of organic molecular structures. Moreover, the coordination mode between the metal cations and organic ligands is flexible, enabling the application of OMCs in a wide variety of low-cost electronic and optoelectronic devices. As an important field of optoelectronic research, the applications of OMCs such as phthalocyanine-, porphyrin-, platinum- and ruthenium-based metal complexes in organic photovoltaic solar cells (OSCs) as the active layer, transport layer and additives are reviewed. The performance enhancements in OSCs are closely related to the structures and properties of OMCs. Herein, we provide an in-depth analysis of the structure-performance relationships of OMCs. Finally, perspectives on the opportunities and challenges of these materials are given. It is hoped that this review will inspire the development of OMCs for advanced OSCs.
Organic-metal complexes (OMCs) are endowed with new functions and properties due to the characteristics of valence changes of metal ions and the diversity of organic molecular structures.</description><subject>Additives</subject><subject>Coordination compounds</subject><subject>Mechanical properties</subject><subject>Molecular structure</subject><subject>Optoelectronic devices</subject><subject>Organic chemistry</subject><subject>Photovoltaic cells</subject><subject>Porphyrins</subject><subject>Ruthenium</subject><subject>Solar cells</subject><issn>2052-1537</issn><issn>2052-1537</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLxDAQgIMouKx78S4UvAnVTKdN2qPs-oIVH-i5pGmydmmbbpIV_fdG6-s0M8zHPD5CDoGeAsXirMZNRymjWO-QSUKzJIYM-e6_fJ_MnFtTSoHzBClMyP2jkqr30WDNyirnoqaPjF2JvpFxp7xoI2m6oVVvykXa2J9eNLwYb15N60UoxDC0jRS-Mb07IHtatE7NvuOUPF9ePM2v4-Xd1c38fBnLJAcfA_IMJShRpwxTKEQKSvKCV1VeI2LKFatzYBlqpHUFaY5VwVkmgGumdXh3So7HueHyzVY5X67N1vZhZZnkvChYzjEJ1MlISWucs0qXg206Yd9LoOWntHKBD7df0hYBPhph6-Qv9ycVPwAQQ2if</recordid><startdate>20231023</startdate><enddate>20231023</enddate><creator>Lv, Qianglong</creator><creator>Yu, Runnan</creator><creator>Shi, Rui</creator><creator>Tan, Zhan'ao</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2700-4725</orcidid></search><sort><creationdate>20231023</creationdate><title>Recent progress in organic-metal complexes for organic photovoltaic applications</title><author>Lv, Qianglong ; Yu, Runnan ; Shi, Rui ; Tan, Zhan'ao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-13753c1ead463419a41ec797bb8d33347e6d81653f30db1483b9765a17f6ff103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Additives</topic><topic>Coordination compounds</topic><topic>Mechanical properties</topic><topic>Molecular structure</topic><topic>Optoelectronic devices</topic><topic>Organic chemistry</topic><topic>Photovoltaic cells</topic><topic>Porphyrins</topic><topic>Ruthenium</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lv, Qianglong</creatorcontrib><creatorcontrib>Yu, Runnan</creatorcontrib><creatorcontrib>Shi, Rui</creatorcontrib><creatorcontrib>Tan, Zhan'ao</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials chemistry frontiers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lv, Qianglong</au><au>Yu, Runnan</au><au>Shi, Rui</au><au>Tan, Zhan'ao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent progress in organic-metal complexes for organic photovoltaic applications</atitle><jtitle>Materials chemistry frontiers</jtitle><date>2023-10-23</date><risdate>2023</risdate><volume>7</volume><issue>21</issue><spage>563</spage><epage>513</epage><pages>563-513</pages><issn>2052-1537</issn><eissn>2052-1537</eissn><abstract>Organic-metal complexes (OMCs) combine the functions of metals with mechanical properties and organic molecules with solution-processing properties, endowing them with the valence change characteristics of metal ions and diversity of organic molecular structures. Moreover, the coordination mode between the metal cations and organic ligands is flexible, enabling the application of OMCs in a wide variety of low-cost electronic and optoelectronic devices. As an important field of optoelectronic research, the applications of OMCs such as phthalocyanine-, porphyrin-, platinum- and ruthenium-based metal complexes in organic photovoltaic solar cells (OSCs) as the active layer, transport layer and additives are reviewed. The performance enhancements in OSCs are closely related to the structures and properties of OMCs. Herein, we provide an in-depth analysis of the structure-performance relationships of OMCs. Finally, perspectives on the opportunities and challenges of these materials are given. It is hoped that this review will inspire the development of OMCs for advanced OSCs.
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| ispartof | Materials chemistry frontiers, 2023-10, Vol.7 (21), p.563-513 |
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| source | Royal Society Of Chemistry Journals |
| subjects | Additives Coordination compounds Mechanical properties Molecular structure Optoelectronic devices Organic chemistry Photovoltaic cells Porphyrins Ruthenium Solar cells |
| title | Recent progress in organic-metal complexes for organic photovoltaic applications |
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