Metal-organic framework-derived trimetallic oxides with dual sensing functions for ethanol
Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. Still, challenges remain for MOF-derived materials, including low-cost and facile synthetic methods,...
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| Veröffentlicht in: | Nanoscale 2023-05, Vol.15 (18), p.8181-8188 |
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| creator | Huang, Xin-Yu Kang, Ya-Ru Yan, Shu Elmarakbi, Ahmed Fu, Yong-Qing Xie, Wan-Feng |
| description | Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. Still, challenges remain for MOF-derived materials, including low-cost and facile synthetic methods, rational nanostructure design, and superior gas-sensing performances. Herein, a series of Fe-MIL-88B-derived trimetallic FeCoNi oxides (FCN-MOS) with a mesoporous structure were synthesized by a one-step hydrothermal reaction followed by calcination. The FCN-MOS system consists of three main phases: α-Fe
2
O
3
(n-type), CoFe
2
O
4
, and NiFe
2
O
4
(p-type), and the nanostructure and pore size can be controlled by altering the content of α-Fe
2
O
3
, CoFe
2
O
4
, and NiFe
2
O
4
. The sensors based on FCN-MOS exhibit a high response of 71.9, a good selectivity towards 100 ppm ethanol at 250 °C, and long-term stability up to 60 days. Additionally, the FCN-MOS-based sensors show a p-n transition gas sensing behavior with the alteration of the Fe/Co/Ni ratio.
Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. |
| doi_str_mv | 10.1039/d3nr00841j |
| format | Article |
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2
O
3
(n-type), CoFe
2
O
4
, and NiFe
2
O
4
(p-type), and the nanostructure and pore size can be controlled by altering the content of α-Fe
2
O
3
, CoFe
2
O
4
, and NiFe
2
O
4
. The sensors based on FCN-MOS exhibit a high response of 71.9, a good selectivity towards 100 ppm ethanol at 250 °C, and long-term stability up to 60 days. Additionally, the FCN-MOS-based sensors show a p-n transition gas sensing behavior with the alteration of the Fe/Co/Ni ratio.
Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d3nr00841j</identifier><identifier>PMID: 37078095</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Cobalt ferrites ; Ethanol ; Ferric oxide ; Gas sensors ; Hydrothermal reactions ; Metal oxide semiconductors ; Metal-organic frameworks ; Nanostructure ; Nickel ferrites ; Pore size ; Porosity</subject><ispartof>Nanoscale, 2023-05, Vol.15 (18), p.8181-8188</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c373t-511a24c21416b8442c48ebb7bbf619627fcc60f58dbece3e0d7cc96c66d7545b3</citedby><cites>FETCH-LOGICAL-c373t-511a24c21416b8442c48ebb7bbf619627fcc60f58dbece3e0d7cc96c66d7545b3</cites><orcidid>0000-0001-8092-0058 ; 0000-0002-5477-7988 ; 0000-0002-7479-3870 ; 0000-0002-0035-5368 ; 0000-0001-9797-4036</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37078095$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Xin-Yu</creatorcontrib><creatorcontrib>Kang, Ya-Ru</creatorcontrib><creatorcontrib>Yan, Shu</creatorcontrib><creatorcontrib>Elmarakbi, Ahmed</creatorcontrib><creatorcontrib>Fu, Yong-Qing</creatorcontrib><creatorcontrib>Xie, Wan-Feng</creatorcontrib><title>Metal-organic framework-derived trimetallic oxides with dual sensing functions for ethanol</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. Still, challenges remain for MOF-derived materials, including low-cost and facile synthetic methods, rational nanostructure design, and superior gas-sensing performances. Herein, a series of Fe-MIL-88B-derived trimetallic FeCoNi oxides (FCN-MOS) with a mesoporous structure were synthesized by a one-step hydrothermal reaction followed by calcination. The FCN-MOS system consists of three main phases: α-Fe
2
O
3
(n-type), CoFe
2
O
4
, and NiFe
2
O
4
(p-type), and the nanostructure and pore size can be controlled by altering the content of α-Fe
2
O
3
, CoFe
2
O
4
, and NiFe
2
O
4
. The sensors based on FCN-MOS exhibit a high response of 71.9, a good selectivity towards 100 ppm ethanol at 250 °C, and long-term stability up to 60 days. Additionally, the FCN-MOS-based sensors show a p-n transition gas sensing behavior with the alteration of the Fe/Co/Ni ratio.
Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture.</description><subject>Cobalt ferrites</subject><subject>Ethanol</subject><subject>Ferric oxide</subject><subject>Gas sensors</subject><subject>Hydrothermal reactions</subject><subject>Metal oxide semiconductors</subject><subject>Metal-organic frameworks</subject><subject>Nanostructure</subject><subject>Nickel ferrites</subject><subject>Pore size</subject><subject>Porosity</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpd0U1LwzAYwPEgiu8X70rAiwjVpEmT9ii-y1QQvXgpafJUO7tkJq3Tb2_m5gRPCTw_HsI_CO1QckQJK44Ns56QnNPhElpPCScJYzJdXtwFX0MbIQwJEQUTbBWtMUlkTopsHT3fQqfaxPkXZRuNa69GMHH-LTHgmw8wuPPNaEraOHWfjYGAJ033ik2vWhzAhsa-4Lq3umucDbh2HkP3qqxrt9BKrdoA2_NzEz1dnD-eXiWD-8vr05NBoplkXZJRqlKuU8qpqHLOU81zqCpZVbWghUhlrbUgdZabCjQwIEZqXQgthJEZzyq2iQ5me8fevfcQunLUBA1tqyy4PpRpHiMJkWYi0v1_dOh6b-ProqI0Z4UkNKrDmdLeheChLscxgvJfJSXltHh5xu4eforfRLw3X9lXIzAL-ps4gt0Z8EEvpn9fxr4BESiGMA</recordid><startdate>20230511</startdate><enddate>20230511</enddate><creator>Huang, Xin-Yu</creator><creator>Kang, Ya-Ru</creator><creator>Yan, Shu</creator><creator>Elmarakbi, Ahmed</creator><creator>Fu, Yong-Qing</creator><creator>Xie, Wan-Feng</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8092-0058</orcidid><orcidid>https://orcid.org/0000-0002-5477-7988</orcidid><orcidid>https://orcid.org/0000-0002-7479-3870</orcidid><orcidid>https://orcid.org/0000-0002-0035-5368</orcidid><orcidid>https://orcid.org/0000-0001-9797-4036</orcidid></search><sort><creationdate>20230511</creationdate><title>Metal-organic framework-derived trimetallic oxides with dual sensing functions for ethanol</title><author>Huang, Xin-Yu ; Kang, Ya-Ru ; Yan, Shu ; Elmarakbi, Ahmed ; Fu, Yong-Qing ; Xie, Wan-Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-511a24c21416b8442c48ebb7bbf619627fcc60f58dbece3e0d7cc96c66d7545b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Cobalt ferrites</topic><topic>Ethanol</topic><topic>Ferric oxide</topic><topic>Gas sensors</topic><topic>Hydrothermal reactions</topic><topic>Metal oxide semiconductors</topic><topic>Metal-organic frameworks</topic><topic>Nanostructure</topic><topic>Nickel ferrites</topic><topic>Pore size</topic><topic>Porosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Xin-Yu</creatorcontrib><creatorcontrib>Kang, Ya-Ru</creatorcontrib><creatorcontrib>Yan, Shu</creatorcontrib><creatorcontrib>Elmarakbi, Ahmed</creatorcontrib><creatorcontrib>Fu, Yong-Qing</creatorcontrib><creatorcontrib>Xie, Wan-Feng</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Xin-Yu</au><au>Kang, Ya-Ru</au><au>Yan, Shu</au><au>Elmarakbi, Ahmed</au><au>Fu, Yong-Qing</au><au>Xie, Wan-Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-organic framework-derived trimetallic oxides with dual sensing functions for ethanol</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2023-05-11</date><risdate>2023</risdate><volume>15</volume><issue>18</issue><spage>8181</spage><epage>8188</epage><pages>8181-8188</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture. Still, challenges remain for MOF-derived materials, including low-cost and facile synthetic methods, rational nanostructure design, and superior gas-sensing performances. Herein, a series of Fe-MIL-88B-derived trimetallic FeCoNi oxides (FCN-MOS) with a mesoporous structure were synthesized by a one-step hydrothermal reaction followed by calcination. The FCN-MOS system consists of three main phases: α-Fe
2
O
3
(n-type), CoFe
2
O
4
, and NiFe
2
O
4
(p-type), and the nanostructure and pore size can be controlled by altering the content of α-Fe
2
O
3
, CoFe
2
O
4
, and NiFe
2
O
4
. The sensors based on FCN-MOS exhibit a high response of 71.9, a good selectivity towards 100 ppm ethanol at 250 °C, and long-term stability up to 60 days. Additionally, the FCN-MOS-based sensors show a p-n transition gas sensing behavior with the alteration of the Fe/Co/Ni ratio.
Metal-organic framework (MOF)-derived metal oxide semiconductors have recently received extensive attention in gas sensing applications due to their high porosity and three-dimensional architecture.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37078095</pmid><doi>10.1039/d3nr00841j</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-8092-0058</orcidid><orcidid>https://orcid.org/0000-0002-5477-7988</orcidid><orcidid>https://orcid.org/0000-0002-7479-3870</orcidid><orcidid>https://orcid.org/0000-0002-0035-5368</orcidid><orcidid>https://orcid.org/0000-0001-9797-4036</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Cobalt ferrites Ethanol Ferric oxide Gas sensors Hydrothermal reactions Metal oxide semiconductors Metal-organic frameworks Nanostructure Nickel ferrites Pore size Porosity |
| title | Metal-organic framework-derived trimetallic oxides with dual sensing functions for ethanol |
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