Fabrication of polyaniline/waste sugarcane bagasse composite fillers for excellent anti-corrosion protective coatings

Herein, biomass-based anti-corrosion composite fillers for water-based epoxy resin coatings, epoxy resin powder coatings, and efficient anticorrosive coatings were successfully prepared. Polyaniline/sugarcane bagasse composites (PANI-SCB) were prepared by in situ polymerization after the sugarcane b...

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Veröffentlicht in:New journal of chemistry 2024-03, Vol.48 (11), p.481-482
Hauptverfasser: Yu, Sidi, Liu, Yuansong, Mo, Rongcan, Li, Ya, Zhou, Zhongyang, Zhang, Liangkun, Fan, Bing, Cao, Yuegang
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container_end_page 482
container_issue 11
container_start_page 481
container_title New journal of chemistry
container_volume 48
creator Yu, Sidi
Liu, Yuansong
Mo, Rongcan
Li, Ya
Zhou, Zhongyang
Zhang, Liangkun
Fan, Bing
Cao, Yuegang
description Herein, biomass-based anti-corrosion composite fillers for water-based epoxy resin coatings, epoxy resin powder coatings, and efficient anticorrosive coatings were successfully prepared. Polyaniline/sugarcane bagasse composites (PANI-SCB) were prepared by in situ polymerization after the sugarcane bagasse was ground into a powder with a planetary ball mill. SEM results showed that a large number of loose polyaniline particles were formed on the surface of bagasse. Electrochemical testing showed that the water-based epoxy resin coating with 1% PANI-SCB had a low corrosion current density (5.466 × 10 −7 A cm −2 ) and the highest low-frequency impedance modulus (34 260 Ω cm −2 ). The high protection efficiency (99.57%) and slow decline in impedance with a long soaking time indicated satisfactory anti-corrosion performance. On this basis, the prepared powder coating with 3% PANI-SCB presented a low corrosion current and high protection efficiency (99.39%). In addition, the powder coating had considerable adhesion fastness, flexibility, and commercially viable chemical resistance. XRD analysis found that the presence of Fe 2 O 3 and Fe 3 O 4 in the corrosion products can effectively induce the formation of a dense passivation film, thereby improving the corrosion resistance. The economic and environmental composite coating is expected to function in the anti-corrosion maintenance of hydropower station facilities. Herein, biomass-based anti-corrosion composite fillers for water-based epoxy resin coatings, epoxy resin powder coatings, and efficient anticorrosive coatings were successfully prepared.
doi_str_mv 10.1039/d3nj05901d
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Polyaniline/sugarcane bagasse composites (PANI-SCB) were prepared by in situ polymerization after the sugarcane bagasse was ground into a powder with a planetary ball mill. SEM results showed that a large number of loose polyaniline particles were formed on the surface of bagasse. Electrochemical testing showed that the water-based epoxy resin coating with 1% PANI-SCB had a low corrosion current density (5.466 × 10 −7 A cm −2 ) and the highest low-frequency impedance modulus (34 260 Ω cm −2 ). The high protection efficiency (99.57%) and slow decline in impedance with a long soaking time indicated satisfactory anti-corrosion performance. On this basis, the prepared powder coating with 3% PANI-SCB presented a low corrosion current and high protection efficiency (99.39%). In addition, the powder coating had considerable adhesion fastness, flexibility, and commercially viable chemical resistance. XRD analysis found that the presence of Fe 2 O 3 and Fe 3 O 4 in the corrosion products can effectively induce the formation of a dense passivation film, thereby improving the corrosion resistance. The economic and environmental composite coating is expected to function in the anti-corrosion maintenance of hydropower station facilities. 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XRD analysis found that the presence of Fe 2 O 3 and Fe 3 O 4 in the corrosion products can effectively induce the formation of a dense passivation film, thereby improving the corrosion resistance. The economic and environmental composite coating is expected to function in the anti-corrosion maintenance of hydropower station facilities. 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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Bagasse
Corrosion
Corrosion currents
Corrosion prevention
Corrosion products
Corrosion resistance
Epoxy resins
Fillers
Hydroelectric power stations
Impedance
Iron oxides
Particulate composites
Polyanilines
Powder coating
Powder coatings
Protective coatings
Sugarcane
title Fabrication of polyaniline/waste sugarcane bagasse composite fillers for excellent anti-corrosion protective coatings
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