Kinetics and mechanism of halide exchange in reactions of CpRu(PPh 3 ) 2 Cl with alkyl halides: evidence for radical pairs

Halide exchange reactions between CpRu(PPh 3 ) 2 Cl (1) and CBr 4 , CHBr 3 , CBr 3 CO 2 Et or CHBr 2 CO 2 Et yielding CpRu(PPh 3 ) 2 Br (3) are facile and appear to proceed by a radical pair intermediate in a second order reaction. The relative reactivity of the bromocarbon compounds follows the ord...

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Veröffentlicht in:	New journal of chemistry 2023-11, Vol.47 (46), p.21404-21410
Hauptverfasser:	Carney, Katherine, Polito, Lauren, Reid, Kamilya, Srinivasan, Surbhi, Blake, Gabrielle, Chintala, Nithin, Dong, Sijia S., Kirss, Rein U.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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