Bicolour, large area, inkjet-printed metal halide perovskite light emitting diodes

We demonstrate a bicoloured metal halide perovskite (MHP) light emitting diode (LED) fabricated in two sequential inkjet printing steps. By adjusting the printing parameters, we selectively and deliberately redissolve and recrystallize the first printed emissive layer to add a pattern emitting in a...

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Veröffentlicht in:Materials horizons 2024-04, Vol.11 (8), p.1989-1996
Hauptverfasser: Schröder, Vincent R. F, Fratzscher, Nicolas, Zorn Morales, Nicolas, Rühl, Daniel Steffen, Hermerschmidt, Felix, Unger, Eva L, List-Kratochvil, Emil J. W
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container_end_page 1996
container_issue 8
container_start_page 1989
container_title Materials horizons
container_volume 11
creator Schröder, Vincent R. F
Fratzscher, Nicolas
Zorn Morales, Nicolas
Rühl, Daniel Steffen
Hermerschmidt, Felix
Unger, Eva L
List-Kratochvil, Emil J. W
description We demonstrate a bicoloured metal halide perovskite (MHP) light emitting diode (LED) fabricated in two sequential inkjet printing steps. By adjusting the printing parameters, we selectively and deliberately redissolve and recrystallize the first printed emissive layer to add a pattern emitting in a different color. The red light emitting features (on a green light emitting background) have a minimum size of 100 μm and originate from iodide-rich domains in a phase-segregated, mixed MHP. This phase forms between the first layer, a bromide-based MHP, which is partially dissolved by printing, and the second layer, an iodide-containing MHP. With an optimised printing process we can retain the active layer integrity and fabricate bicolour, large area MHP-based LEDs with up to 1600 mm 2 active area. The two emission peaks at 535 nm and 710 nm are well separated and produce a strong visual contrast. Using a sequential inkjet printing process, we realize bicoloured PeLEDs by selectively dissolving a bromide-based perovskite film with an iodide-based perovskite ink, resulting in red light-emitting features on a green light-emitting background.
doi_str_mv 10.1039/d3mh02025h
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source SWEPUB Freely available online; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical Sciences
Inkjet printing
Kemi
Light emitting diodes
Materialkemi
Materials Chemistry
Metal halides
Natural Sciences
Naturvetenskap
Perovskites
title Bicolour, large area, inkjet-printed metal halide perovskite light emitting diodes
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