Scalable functionalized liquid crystal elastomer fiber soft actuators with multi-stimulus responses and photoelectric conversion

Liquid crystal elastomer (LCE) fibers exhibit large deformation and reversibility, making them an ideal candidate for soft actuators. It is still challenging to develop a scalable strategy and endow fiber actuators with photoelectric functions to achieve tailorable photo-electro-thermal responsiveness and rapid large actuation deformation. Herein, we fabricated a multiresponsive actuator that consists of LCE long fibers obtained by continuous dry spinning and further coated it with polydopamine (PDA)-modified MXene ink. The designed PDA@MXene-integrated LCE fiber is used for shape-deformable and multi-trigger actuators that can be photo- and electro-thermally actuated. The proposed LCE fiber actuator combines an excellent photothermal and long-term electrically conductive PDA@MXene and a shape-morphing LCE fiber, enabling their robust mechanical flexibility, multiple fast responses (∼0.4 s), and stable and large actuation deformation (∼60%). As a proof-of-concept, we present near-infrared light-driven artificial muscle that can lift 1000 times the weight and an intelligent circuit switch with stable controllability and fast responsiveness (∼0.1 s). Importantly, an adaptive smart window system that integrates light-driven energy harvesting/conversion functions is ingeniously constructed by the integration of a propellable curtain woven by the designed fiber and solar cells. This work can provide insights into the development of advanced intelligent materials toward soft robotics, sustainable energy savings and beyond. Scalable multi-responsive LCE fiber actuators were fabricated and used to manufacture artificial muscles, smart circuit switches and adaptive smart windows.