High-resolution rovibrational and rotational spectroscopy of the singly deuterated cyclopropenyl cation, c-C 3 H 2 D

High-resolution rovibrational and rotational spectroscopy of the singly deuterated cyclopropenyl cation, c-C 3 H 2 D

Applying a novel action spectroscopic technique in a 4 K cryogenic ion-trap instrument, the molecule c-C H D has been investigated by high-resolution rovibrational and pure rotational spectroscopy for the first time. In total, 126 rovibrational transitions within the fundamental band of the symmetri...

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Veröffentlicht in:Faraday discussions 2023-09, Vol.245, p.298-308
Hauptverfasser: Gupta, Divita, Silva, Weslley G D P, Doménech, José L, Plaar, Eline, Thorwirth, Sven, Schlemmer, Stephan, Asvany, Oskar
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container_title Faraday discussions
container_volume 245
creator Gupta, Divita
Silva, Weslley G D P
Doménech, José L
Plaar, Eline
Thorwirth, Sven
Schlemmer, Stephan
Asvany, Oskar
description Applying a novel action spectroscopic technique in a 4 K cryogenic ion-trap instrument, the molecule c-C H D has been investigated by high-resolution rovibrational and pure rotational spectroscopy for the first time. In total, 126 rovibrational transitions within the fundamental band of the symmetric C-H stretch were measured with a band origin centred at 3168.565 cm , which were used to predict pure rotational transition frequencies in the ground vibrational state. Based on these predictions, 16 rotational transitions were observed between 90 and 230 GHz by using a double-resonance scheme. These new measurements will enable the first radio-astronomical search for c-C H D .
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title High-resolution rovibrational and rotational spectroscopy of the singly deuterated cyclopropenyl cation, c-C 3 H 2 D
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