High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]
The inorganic pyrocarbonate salt Na [C O ] crystallizes in the acentric, monoclinic space group 2 with = 2. It contains monovalent alkali metal cations together with isolated pyrocarbonate anions. The [C O ] -groups consist of two planar [CO ] -groups which are slightly tilted with respect to each o...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-12, Vol.53 (1), p.40-44 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Spahr, Dominik Bayarjargal, Lkhamsuren Bykov, Maxim Brüning, Lukas Reuter, Tim H Milman, Victor Liermann, Hanns-Peter Winkler, Björn |
| description | The inorganic pyrocarbonate salt Na
[C
O
] crystallizes in the acentric, monoclinic space group
2
with
= 2. It contains monovalent alkali metal cations together with isolated pyrocarbonate anions. The [C
O
]
-groups consist of two planar [CO
]
-groups which are slightly tilted with respect to each other around the bridging oxygen atom. Na
[C
O
] was synthesized in a laser-heated diamond anvil cell at 20(2) GPa by heating a mixture of Na
[CO
] + CO
to ≈800(200) K. Its crystal structure was obtained by single crystal synchrotron X-ray diffraction and confirmed by density functional theory-based calculations in combination with Raman spectroscopy. Second harmonic generation measurements verified the acentric space group symmetry. The crystal structure is characterized by alternating layers of Na
-cations and [C
O
]
-complex anions. |
| doi_str_mv | 10.1039/D3DT03673A |
| format | Article |
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[C
O
] crystallizes in the acentric, monoclinic space group
2
with
= 2. It contains monovalent alkali metal cations together with isolated pyrocarbonate anions. The [C
O
]
-groups consist of two planar [CO
]
-groups which are slightly tilted with respect to each other around the bridging oxygen atom. Na
[C
O
] was synthesized in a laser-heated diamond anvil cell at 20(2) GPa by heating a mixture of Na
[CO
] + CO
to ≈800(200) K. Its crystal structure was obtained by single crystal synchrotron X-ray diffraction and confirmed by density functional theory-based calculations in combination with Raman spectroscopy. Second harmonic generation measurements verified the acentric space group symmetry. The crystal structure is characterized by alternating layers of Na
-cations and [C
O
]
-complex anions.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/D3DT03673A</identifier><identifier>PMID: 38054559</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-12, Vol.53 (1), p.40-44</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c999-9291d2e0dbc0bb936757878b6f8d25b99fb368fccf9cb80dc0ff478245fc25d23</citedby><cites>FETCH-LOGICAL-c999-9291d2e0dbc0bb936757878b6f8d25b99fb368fccf9cb80dc0ff478245fc25d23</cites><orcidid>0000-0003-2258-1347 ; 0000-0002-5513-591X ; 0000-0003-0489-5270 ; 0000-0003-0248-1728 ; 0009-0006-0630-0321</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38054559$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Spahr, Dominik</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Bykov, Maxim</creatorcontrib><creatorcontrib>Brüning, Lukas</creatorcontrib><creatorcontrib>Reuter, Tim H</creatorcontrib><creatorcontrib>Milman, Victor</creatorcontrib><creatorcontrib>Liermann, Hanns-Peter</creatorcontrib><creatorcontrib>Winkler, Björn</creatorcontrib><title>High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The inorganic pyrocarbonate salt Na
[C
O
] crystallizes in the acentric, monoclinic space group
2
with
= 2. It contains monovalent alkali metal cations together with isolated pyrocarbonate anions. The [C
O
]
-groups consist of two planar [CO
]
-groups which are slightly tilted with respect to each other around the bridging oxygen atom. Na
[C
O
] was synthesized in a laser-heated diamond anvil cell at 20(2) GPa by heating a mixture of Na
[CO
] + CO
to ≈800(200) K. Its crystal structure was obtained by single crystal synchrotron X-ray diffraction and confirmed by density functional theory-based calculations in combination with Raman spectroscopy. Second harmonic generation measurements verified the acentric space group symmetry. The crystal structure is characterized by alternating layers of Na
-cations and [C
O
]
-complex anions.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpFkMtOwzAURC0EoqWw4QOQ14jAjR3H9rJKgVaq6CY7hKL4RYPIQ3ayyN83qFA2d-7iaDQzCN3G8BgDlU8rusqBppwuz9A8TjiPJKHJ-ekn6QxdhfAFQAgwcolmVABLGJNztFlXn_uo8zaEwVscxqbf21AF3Dpcatv0vtI4tKYaatyNvtWlV21T9vYBv5WY4PdsOjvM8Mc1unDld7A3v7pA-ctznq2j7e51ky23kZZSTmlkbIgFozQoJafUjAsuVOqEIUxJ6RRNhdPaSa0EGA3OJVyQhDlNmCF0ge6Pttq3IXjris5XdenHIobiZ47if44JvjvC3aBqa07oX396AKmAWPQ</recordid><startdate>20231219</startdate><enddate>20231219</enddate><creator>Spahr, Dominik</creator><creator>Bayarjargal, Lkhamsuren</creator><creator>Bykov, Maxim</creator><creator>Brüning, Lukas</creator><creator>Reuter, Tim H</creator><creator>Milman, Victor</creator><creator>Liermann, Hanns-Peter</creator><creator>Winkler, Björn</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2258-1347</orcidid><orcidid>https://orcid.org/0000-0002-5513-591X</orcidid><orcidid>https://orcid.org/0000-0003-0489-5270</orcidid><orcidid>https://orcid.org/0000-0003-0248-1728</orcidid><orcidid>https://orcid.org/0009-0006-0630-0321</orcidid></search><sort><creationdate>20231219</creationdate><title>High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]</title><author>Spahr, Dominik ; Bayarjargal, Lkhamsuren ; Bykov, Maxim ; Brüning, Lukas ; Reuter, Tim H ; Milman, Victor ; Liermann, Hanns-Peter ; Winkler, Björn</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c999-9291d2e0dbc0bb936757878b6f8d25b99fb368fccf9cb80dc0ff478245fc25d23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Spahr, Dominik</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Bykov, Maxim</creatorcontrib><creatorcontrib>Brüning, Lukas</creatorcontrib><creatorcontrib>Reuter, Tim H</creatorcontrib><creatorcontrib>Milman, Victor</creatorcontrib><creatorcontrib>Liermann, Hanns-Peter</creatorcontrib><creatorcontrib>Winkler, Björn</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Spahr, Dominik</au><au>Bayarjargal, Lkhamsuren</au><au>Bykov, Maxim</au><au>Brüning, Lukas</au><au>Reuter, Tim H</au><au>Milman, Victor</au><au>Liermann, Hanns-Peter</au><au>Winkler, Björn</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-12-19</date><risdate>2023</risdate><volume>53</volume><issue>1</issue><spage>40</spage><epage>44</epage><pages>40-44</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The inorganic pyrocarbonate salt Na
[C
O
] crystallizes in the acentric, monoclinic space group
2
with
= 2. It contains monovalent alkali metal cations together with isolated pyrocarbonate anions. The [C
O
]
-groups consist of two planar [CO
]
-groups which are slightly tilted with respect to each other around the bridging oxygen atom. Na
[C
O
] was synthesized in a laser-heated diamond anvil cell at 20(2) GPa by heating a mixture of Na
[CO
] + CO
to ≈800(200) K. Its crystal structure was obtained by single crystal synchrotron X-ray diffraction and confirmed by density functional theory-based calculations in combination with Raman spectroscopy. Second harmonic generation measurements verified the acentric space group symmetry. The crystal structure is characterized by alternating layers of Na
-cations and [C
O
]
-complex anions.</abstract><cop>England</cop><pmid>38054559</pmid><doi>10.1039/D3DT03673A</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-2258-1347</orcidid><orcidid>https://orcid.org/0000-0002-5513-591X</orcidid><orcidid>https://orcid.org/0000-0003-0489-5270</orcidid><orcidid>https://orcid.org/0000-0003-0248-1728</orcidid><orcidid>https://orcid.org/0009-0006-0630-0321</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-12, Vol.53 (1), p.40-44 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D3DT03673A |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ] |
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