Predictable electronic tuning of Fe II and Ru II complexes via choice of azine: correlation of ligand p K a with E pa (M III/II ) of complex

Five new mononuclear ruthenium(II) tris-ligated complexes have been synthesised, varying through the choice of azine in the family of 3-azinyl-4-(4-methylphenyl)-5-phenyl-4 -1,2,4-triazole ligands (Lazine): [Ru(Lpyridine)](PF ) (1), [Ru(Lpyridazine)](PF ) (2), [Ru(L4-pyrimidine)](PF ) (3), [Ru(Lpyra...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-01, Vol.53 (5), p.1999-2007
Hauptverfasser:	Robb, Matthew G, Bondì, Luca, Rodríguez-Jiménez, Santiago, Garden, Anna L, Jerabek, Paul, Brooker, Sally
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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