A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries
Lithium-sulfur batteries (LSBs) have emerged as one of the ideal contenders for the upcoming generation of high energy storage devices due to their superb energy density. Nonetheless, the shuttle effect generated by intermediate lithium polysulfides (LiPSs) during cell cycling brings about capacity...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-07, Vol.52 (26), p.932-941 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 941 |
|---|---|
| container_issue | 26 |
| container_start_page | 932 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Su, Zhuoying Qiu, Wenjuan He, Yuming Zeng, Ying Xie, Dongming Xiao, Xin Nan, Junmin Zuo, Xiaoxi |
| description | Lithium-sulfur batteries (LSBs) have emerged as one of the ideal contenders for the upcoming generation of high energy storage devices due to their superb energy density. Nonetheless, the shuttle effect generated by intermediate lithium polysulfides (LiPSs) during cell cycling brings about capacity degradation and poor cycling stability of LSBs. Here, a versatile SrFe
12
O
19
(FSO) and acetylene black (AB) modified PP separator is first presented to inhibit the shuttle effect. Thanks to the strong chemical interaction of Fe and Sr with polysulphides in FSO, it can trap LiPSs and provide catalytic sites for their conversion. Therefore, the cell using the FSO/AB@PP separator has a high initial discharge specific capacity (930 mA h g
−1
) at 2 C and lasts for 1000 cycles with a remarkably low fading rate (0.036% per cycle), while those using PE and AB@PP separators have inferior initial specific capacities (255 mA h g
−1
and 652 mA h g
−1
, respectively) and fail within 600 cycles. This work proposes a novel approach for addressing the shuttle of LiPSs from a bimetallic oxide modified separator.
Bimetallic oxide SrFe
12
O
19
/AB composite separator regulates lithium polysulfides to realize sustainable lithium-sulfur batteries. |
| doi_str_mv | 10.1039/d3dt01126g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D3DT01126G</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2827920760</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-378bc6b74c6b1282e3cb5e81d00f4c0f21767053f6e60845b129a0cf7d1e50993</originalsourceid><addsrcrecordid>eNpdkc1q3DAUhUVpaJJJNt23CLoJAaeSrm2NlyH_MJBNujaydNUq2JYryaHzAHnvaDLJFLK4uoLz6ejAIeQrZ2ecQfPTgEmMc1H__kQOeCll0QgoP-_uot4nhzE-MiYEq8QXsg8SoBIVHJDncxpT8GNy80AthuAS0sEbZx0aGnFSQSUfqM2jTPRhSs6PVI2GapVUv05OU-3HJwxxI3hLJ9-v49xbZzC-vsN_Gvsex0R7l_7kj4qNPAfaqZQwOIxHZM-qPuLx216QX9dXDxe3xer-5u7ifFVoAJkKkMtO150s88HFUiDorsIlN4zZUjMruKwlq8DWWLNlWWWoUUxbaThWrGlgQU62vlPwf2eMqR1c3IRTI_o5ttlTNoLJmmX0xwf00c9hzOkyBaJuBOeQqdMtpYOPMaBtp-AGFdYtZ-2mnPYSLh9ey7nJ8Pc3y7kb0OzQ9zYy8G0LhKh36v924QViaJYU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2832692113</pqid></control><display><type>article</type><title>A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Su, Zhuoying ; Qiu, Wenjuan ; He, Yuming ; Zeng, Ying ; Xie, Dongming ; Xiao, Xin ; Nan, Junmin ; Zuo, Xiaoxi</creator><creatorcontrib>Su, Zhuoying ; Qiu, Wenjuan ; He, Yuming ; Zeng, Ying ; Xie, Dongming ; Xiao, Xin ; Nan, Junmin ; Zuo, Xiaoxi</creatorcontrib><description>Lithium-sulfur batteries (LSBs) have emerged as one of the ideal contenders for the upcoming generation of high energy storage devices due to their superb energy density. Nonetheless, the shuttle effect generated by intermediate lithium polysulfides (LiPSs) during cell cycling brings about capacity degradation and poor cycling stability of LSBs. Here, a versatile SrFe
12
O
19
(FSO) and acetylene black (AB) modified PP separator is first presented to inhibit the shuttle effect. Thanks to the strong chemical interaction of Fe and Sr with polysulphides in FSO, it can trap LiPSs and provide catalytic sites for their conversion. Therefore, the cell using the FSO/AB@PP separator has a high initial discharge specific capacity (930 mA h g
−1
) at 2 C and lasts for 1000 cycles with a remarkably low fading rate (0.036% per cycle), while those using PE and AB@PP separators have inferior initial specific capacities (255 mA h g
−1
and 652 mA h g
−1
, respectively) and fail within 600 cycles. This work proposes a novel approach for addressing the shuttle of LiPSs from a bimetallic oxide modified separator.
Bimetallic oxide SrFe
12
O
19
/AB composite separator regulates lithium polysulfides to realize sustainable lithium-sulfur batteries.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt01126g</identifier><identifier>PMID: 37335253</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acetylene ; Bimetals ; Catalytic converters ; Conversion ; Cycles ; Energy storage ; Lithium ; Lithium sulfur batteries ; Polysulfides ; Separators</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-07, Vol.52 (26), p.932-941</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-378bc6b74c6b1282e3cb5e81d00f4c0f21767053f6e60845b129a0cf7d1e50993</citedby><cites>FETCH-LOGICAL-c337t-378bc6b74c6b1282e3cb5e81d00f4c0f21767053f6e60845b129a0cf7d1e50993</cites><orcidid>0000-0002-2253-1756 ; 0000-0002-8434-0533 ; 0000-0001-6862-8978</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37335253$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Su, Zhuoying</creatorcontrib><creatorcontrib>Qiu, Wenjuan</creatorcontrib><creatorcontrib>He, Yuming</creatorcontrib><creatorcontrib>Zeng, Ying</creatorcontrib><creatorcontrib>Xie, Dongming</creatorcontrib><creatorcontrib>Xiao, Xin</creatorcontrib><creatorcontrib>Nan, Junmin</creatorcontrib><creatorcontrib>Zuo, Xiaoxi</creatorcontrib><title>A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Lithium-sulfur batteries (LSBs) have emerged as one of the ideal contenders for the upcoming generation of high energy storage devices due to their superb energy density. Nonetheless, the shuttle effect generated by intermediate lithium polysulfides (LiPSs) during cell cycling brings about capacity degradation and poor cycling stability of LSBs. Here, a versatile SrFe
12
O
19
(FSO) and acetylene black (AB) modified PP separator is first presented to inhibit the shuttle effect. Thanks to the strong chemical interaction of Fe and Sr with polysulphides in FSO, it can trap LiPSs and provide catalytic sites for their conversion. Therefore, the cell using the FSO/AB@PP separator has a high initial discharge specific capacity (930 mA h g
−1
) at 2 C and lasts for 1000 cycles with a remarkably low fading rate (0.036% per cycle), while those using PE and AB@PP separators have inferior initial specific capacities (255 mA h g
−1
and 652 mA h g
−1
, respectively) and fail within 600 cycles. This work proposes a novel approach for addressing the shuttle of LiPSs from a bimetallic oxide modified separator.
Bimetallic oxide SrFe
12
O
19
/AB composite separator regulates lithium polysulfides to realize sustainable lithium-sulfur batteries.</description><subject>Acetylene</subject><subject>Bimetals</subject><subject>Catalytic converters</subject><subject>Conversion</subject><subject>Cycles</subject><subject>Energy storage</subject><subject>Lithium</subject><subject>Lithium sulfur batteries</subject><subject>Polysulfides</subject><subject>Separators</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkc1q3DAUhUVpaJJJNt23CLoJAaeSrm2NlyH_MJBNujaydNUq2JYryaHzAHnvaDLJFLK4uoLz6ejAIeQrZ2ecQfPTgEmMc1H__kQOeCll0QgoP-_uot4nhzE-MiYEq8QXsg8SoBIVHJDncxpT8GNy80AthuAS0sEbZx0aGnFSQSUfqM2jTPRhSs6PVI2GapVUv05OU-3HJwxxI3hLJ9-v49xbZzC-vsN_Gvsex0R7l_7kj4qNPAfaqZQwOIxHZM-qPuLx216QX9dXDxe3xer-5u7ifFVoAJkKkMtO150s88HFUiDorsIlN4zZUjMruKwlq8DWWLNlWWWoUUxbaThWrGlgQU62vlPwf2eMqR1c3IRTI_o5ttlTNoLJmmX0xwf00c9hzOkyBaJuBOeQqdMtpYOPMaBtp-AGFdYtZ-2mnPYSLh9ey7nJ8Pc3y7kb0OzQ9zYy8G0LhKh36v924QViaJYU</recordid><startdate>20230704</startdate><enddate>20230704</enddate><creator>Su, Zhuoying</creator><creator>Qiu, Wenjuan</creator><creator>He, Yuming</creator><creator>Zeng, Ying</creator><creator>Xie, Dongming</creator><creator>Xiao, Xin</creator><creator>Nan, Junmin</creator><creator>Zuo, Xiaoxi</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2253-1756</orcidid><orcidid>https://orcid.org/0000-0002-8434-0533</orcidid><orcidid>https://orcid.org/0000-0001-6862-8978</orcidid></search><sort><creationdate>20230704</creationdate><title>A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries</title><author>Su, Zhuoying ; Qiu, Wenjuan ; He, Yuming ; Zeng, Ying ; Xie, Dongming ; Xiao, Xin ; Nan, Junmin ; Zuo, Xiaoxi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-378bc6b74c6b1282e3cb5e81d00f4c0f21767053f6e60845b129a0cf7d1e50993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acetylene</topic><topic>Bimetals</topic><topic>Catalytic converters</topic><topic>Conversion</topic><topic>Cycles</topic><topic>Energy storage</topic><topic>Lithium</topic><topic>Lithium sulfur batteries</topic><topic>Polysulfides</topic><topic>Separators</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Su, Zhuoying</creatorcontrib><creatorcontrib>Qiu, Wenjuan</creatorcontrib><creatorcontrib>He, Yuming</creatorcontrib><creatorcontrib>Zeng, Ying</creatorcontrib><creatorcontrib>Xie, Dongming</creatorcontrib><creatorcontrib>Xiao, Xin</creatorcontrib><creatorcontrib>Nan, Junmin</creatorcontrib><creatorcontrib>Zuo, Xiaoxi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Su, Zhuoying</au><au>Qiu, Wenjuan</au><au>He, Yuming</au><au>Zeng, Ying</au><au>Xie, Dongming</au><au>Xiao, Xin</au><au>Nan, Junmin</au><au>Zuo, Xiaoxi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-07-04</date><risdate>2023</risdate><volume>52</volume><issue>26</issue><spage>932</spage><epage>941</epage><pages>932-941</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Lithium-sulfur batteries (LSBs) have emerged as one of the ideal contenders for the upcoming generation of high energy storage devices due to their superb energy density. Nonetheless, the shuttle effect generated by intermediate lithium polysulfides (LiPSs) during cell cycling brings about capacity degradation and poor cycling stability of LSBs. Here, a versatile SrFe
12
O
19
(FSO) and acetylene black (AB) modified PP separator is first presented to inhibit the shuttle effect. Thanks to the strong chemical interaction of Fe and Sr with polysulphides in FSO, it can trap LiPSs and provide catalytic sites for their conversion. Therefore, the cell using the FSO/AB@PP separator has a high initial discharge specific capacity (930 mA h g
−1
) at 2 C and lasts for 1000 cycles with a remarkably low fading rate (0.036% per cycle), while those using PE and AB@PP separators have inferior initial specific capacities (255 mA h g
−1
and 652 mA h g
−1
, respectively) and fail within 600 cycles. This work proposes a novel approach for addressing the shuttle of LiPSs from a bimetallic oxide modified separator.
Bimetallic oxide SrFe
12
O
19
/AB composite separator regulates lithium polysulfides to realize sustainable lithium-sulfur batteries.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37335253</pmid><doi>10.1039/d3dt01126g</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-2253-1756</orcidid><orcidid>https://orcid.org/0000-0002-8434-0533</orcidid><orcidid>https://orcid.org/0000-0001-6862-8978</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-07, Vol.52 (26), p.932-941 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_D3DT01126G |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Acetylene Bimetals Catalytic converters Conversion Cycles Energy storage Lithium Lithium sulfur batteries Polysulfides Separators |
| title | A strontium ferrite modified separator for adsorption and catalytic conversion of polysulfides for excellent lithium-sulfur batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T21%3A05%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20strontium%20ferrite%20modified%20separator%20for%20adsorption%20and%20catalytic%20conversion%20of%20polysulfides%20for%20excellent%20lithium-sulfur%20batteries&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Su,%20Zhuoying&rft.date=2023-07-04&rft.volume=52&rft.issue=26&rft.spage=932&rft.epage=941&rft.pages=932-941&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d3dt01126g&rft_dat=%3Cproquest_cross%3E2827920760%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2832692113&rft_id=info:pmid/37335253&rfr_iscdi=true |